Benzene, 1-methyl-2-(methylsulfinyl)-

Base Information

Chemical Name:Benzene, 1-methyl-2-(methylsulfinyl)-
CAS No.:7321-56-4
Molecular Formula:C8H10OS
Molecular Weight:154.233
Hs Code.:
DSSTox Substance ID:DTXSID70415889
Nikkaji Number:J380.985D

Synonyms:7321-56-4;Benzene, 1-methyl-2-(methylsulfinyl)-;o-tolyl methyl sulfoxide;SCHEMBL1642155;DTXSID70415889;Methyl (2-methylphenyl) sulfoxide

Suppliers and Price of Benzene, 1-methyl-2-(methylsulfinyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Benzene, 1-methyl-2-(methylsulfinyl)-

Chemical Property:

Vapor Pressure:0.00371mmHg at 25°C
XLogP3:1.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:154.04523611
Heavy Atom Count:10
Complexity:133

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=CC=C1S(=O)C

Technology Process of Benzene, 1-methyl-2-(methylsulfinyl)-

There total 5 articles about Benzene, 1-methyl-2-(methylsulfinyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 67-68-5,8070-53-9
dimethyl sulfoxide

: 137-06-4
2-thiocresol

: 7321-56-4
1-methyl-2-(methylsulfinyl)benzene

Guidance literature:: With ammonium perchlorate; water; dihydrogen peroxide; iron(II) chloride; at 20 ℃; for 7.5h; Electrolysis; Green chemistry;
DOI:10.1039/c7gc03864j

Reference yield:

: 676-85-7
methylsulphinyl chloride

: 95-46-5
2-methylphenyl bromide

: 7321-56-4
1-methyl-2-(methylsulfinyl)benzene

Guidance literature:: 2-methylphenyl bromide; With magnesium; at 20 ℃; for 0.5h; Inert atmosphere;

methylsulphinyl chloride; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1002/ejoc.201800907

Reference yield:

: 137-06-4
2-thiocresol

: 7321-56-4
1-methyl-2-(methylsulfinyl)benzene

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydroxide / ethanol / 0.5 h

1.2: 3 h / 20 °C

2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 16 h / 0 °C

With 3-chloro-benzenecarboperoxoic acid; sodium hydroxide; In ethanol; dichloromethane;
DOI:10.1002/adsc.201300766