4-Hydroxy-3-methylidenehexan-2-one

Base Information

Chemical Name:4-Hydroxy-3-methylidenehexan-2-one
CAS No.:73255-30-8
Molecular Formula:C₇H₁₂O₂
Molecular Weight:128.171
Hs Code.:
DSSTox Substance ID:DTXSID70451141
Nikkaji Number:J1.047.411F

Synonyms:4-hydroxy-3-methylidenehexan-2-one;73255-30-8;2-Hexanone, 4-hydroxy-3-methylene-;3-(1-hydroxypropyl)-3-buten-2-one;DTXSID70451141;3-Methylene-4-hydroxy-2-hexanone

Suppliers and Price of 4-Hydroxy-3-methylidenehexan-2-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 4-Hydroxy-3-methylidenehexan-2-one

Chemical Property:

XLogP3:0.6
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:128.083729621
Heavy Atom Count:9
Complexity:127

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCC(C(=C)C(=O)C)O

Technology Process of 4-Hydroxy-3-methylidenehexan-2-one

There total 2 articles about 4-Hydroxy-3-methylidenehexan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 123-38-6
propionaldehyde

: 78-94-4,25038-87-3
methyl vinyl ketone

: 73255-30-8,500297-54-1,136378-00-2
(+/-)-3-(1-hydroxypropyl)but-3-en-2-one

Guidance literature:: With (1,3,5-triaza-7-phosphaadamantane); In tetrahydrofuran; at 20 ℃; for 5h;
DOI:10.1002/adsc.200505403

Reference yield: 77.0%

: 123-38-6
propionaldehyde

: 78-94-4,25038-87-3
methyl vinyl ketone

: 22289-05-0
3-methyleneheptane-2,6-dione

: 73255-30-8,500297-54-1,136378-00-2
(+/-)-3-(1-hydroxypropyl)but-3-en-2-one

Guidance literature:: With isopropyl alcohol; dihydridotetrakis(triphenylphosphine)ruthenium; at 40 ℃; for 40h;
DOI:10.1016/0022-328X(88)80561-8

Reference yield: 95.0%

: 128796-39-4
4-trifluoromethylphenylboronic acid

: 73255-30-8,500297-54-1,136378-00-2
(+/-)-3-(1-hydroxypropyl)but-3-en-2-one

: 1163120-13-5
(E)-3-(4-trifluoromethylbenzyl)hex-3-en-2-one

Guidance literature:: With [Rh(OH)(cod)]2; In methanol; at 20 ℃; optical yield given as %de; stereoselective reaction; Inert atmosphere;
DOI:10.1002/chem.200802276