Dimethyl 3-[2-(2,4-dinitrophenyl)hydrazinylidene]pentanedioate

Base Information

Chemical Name:Dimethyl 3-[2-(2,4-dinitrophenyl)hydrazinylidene]pentanedioate
CAS No.:73591-43-2
Molecular Formula:C13H14N4O8
Molecular Weight:354.276
Hs Code.:
DSSTox Substance ID:DTXSID60577364

Synonyms:73591-43-2;DTXSID60577364;Dimethyl 3-[2-(2,4-dinitrophenyl)hydrazinylidene]pentanedioate

Suppliers and Price of Dimethyl 3-[2-(2,4-dinitrophenyl)hydrazinylidene]pentanedioate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of Dimethyl 3-[2-(2,4-dinitrophenyl)hydrazinylidene]pentanedioate

Chemical Property:

XLogP3:3.1
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:10
Rotatable Bond Count:8
Exact Mass:354.08116342
Heavy Atom Count:25
Complexity:533

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)CC(=NNC1=C(C=C(C=C1)[N+](=O)[O-])[N+](=O)[O-])CC(=O)OC

Technology Process of Dimethyl 3-[2-(2,4-dinitrophenyl)hydrazinylidene]pentanedioate

There total 1 articles about Dimethyl 3-[2-(2,4-dinitrophenyl)hydrazinylidene]pentanedioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.9%

: 1830-54-2
3-oxopentanedioic acid dimethyl ester

: 119-26-6
(2,4-dinitro-phenyl)-hydrazine

: 73591-43-2
Dimethyl 1,3-Acetonedicarboxylate (2,4-Dinitrophenyl)hydrazone

Guidance literature:: With sulfuric acid; In methanol; water; for 2h;
DOI:10.1002/jhet.5570170132

Reference yield: 90.0%

: 73591-43-2
Dimethyl 1,3-Acetonedicarboxylate (2,4-Dinitrophenyl)hydrazone

: 73591-44-3
Methyl 5-Methoxycarbonylmethyl-1-(2,4-dinitroanilino)-1,2,3-triazole-4-carboxylate

Guidance literature:: With 4-toluenesulfonyl azide; 1,5-Diazabicyclo[5.4.0]undec-5-ene; In ethyl acetate; for 1h; Ambient temperature;
DOI:10.1002/jhet.5570170132

Reference yield:

: 73591-43-2
Dimethyl 1,3-Acetonedicarboxylate (2,4-Dinitrophenyl)hydrazone

: 73591-51-2
Methyl 5-Cyanomethyl-2-(2,3,5-tri-O-benzoyl-β-D-ribofuranosyl)-1,2,3-triazole-4-carboxylate

Guidance literature:: Multi-step reaction with 5 steps

1: 90 percent / p-toluenesulfonyl azide, 1,5-diazabicyclo<5.4.0>undec-5-ene / ethyl acetate / 1 h / Ambient temperature

2: 82.3 percent / hydrogen / platinum oxide / acetic acid; 2-methoxy-ethanol / 4 h / 1810.02 Torr / Ambient temperature

3: 54.3 percent / conc. ammonium hydroxide / 8 h / Ambient temperature

4: 78.3 percent / phosphoryl chloride / 1.5 h / Heating

5: 77 percent / 1.) hexamethyldisilazane, ammonium sulfate; 2.) stannic chloride / 1.) reflux, 15 h; 2.) 1,2-dichloroethane, 20 h, r.t.

With ammonium hydroxide; ammonium sulfate; 4-toluenesulfonyl azide; hydrogen; tin(IV) chloride; 1,1,1,3,3,3-hexamethyl-disilazane; 1,5-Diazabicyclo[5.4.0]undec-5-ene; trichlorophosphate; platinum(IV) oxide; In 2-methoxy-ethanol; acetic acid; ethyl acetate;
DOI:10.1002/jhet.5570170132