Propanedioic acid, 3-butenyl-, dimethyl ester

Base Information

Chemical Name:Propanedioic acid, 3-butenyl-, dimethyl ester
CAS No.:74090-14-5
Molecular Formula:C9H14O4
Molecular Weight:186.208
Hs Code.:

Synonyms:dimethyl but-3-en-1-ylmalonate;methyl 2-methoxycarbonyl-5-hexenoate;dimethyl 2-(3-butenyl)malonate;dimethyl 2-(3'-butenyl)malonate;dimethyl 2-(but-3-enyl)malonate;dimethyl 2-(but-3'-enyl)malonate;

Suppliers and Price of Propanedioic acid, 3-butenyl-, dimethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of Propanedioic acid, 3-butenyl-, dimethyl ester

Chemical Property:

PSA：52.60000
LogP:0.91480

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

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Technology Process of Propanedioic acid, 3-butenyl-, dimethyl ester

There total 1 articles about Propanedioic acid, 3-butenyl-, dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 7766-51-0
4-iodobut-1-ene

: 108-59-8
malonic acid dimethyl ester

: 74090-14-5
dimethyl 2-(3-butenyl)malonate

Guidance literature:: With sodium hydride; for 43h; Heating;
DOI:10.1021/jo00005a027

Reference yield: 100.0%

: 74090-14-5
dimethyl 2-(3-butenyl)malonate

: 160879-62-9
methyl 1-phenylprop-2-enyl carbonate

: 389633-72-1
dimethyl 2-(but-3-enyl)-2-[(S)-1-phenylallyl]malonate

Guidance literature:: dimethyl 2-(3-butenyl)malonate; With Wilkinson's catalyst; sodium hydride; phosphorous acid trimethyl ester; In tetrahydrofuran; at 20 ℃; Inert atmosphere; Schlenk technique;

methyl 1-phenylprop-2-enyl carbonate; In tetrahydrofuran; at 30 ℃; for 6h; Inert atmosphere;
DOI:10.1002/anie.201607752

Reference yield: 95.0%

: 74090-14-5
dimethyl 2-(3-butenyl)malonate

: 87751-69-7
rac-(E)-1,3-diphenyl-3-acetoxy-prop-1-ene

: 1252027-86-3
(R,E)-dimethyl 2-(but-3-en-1-yl)-2-(1,3-diphenylallyl)malonate

Guidance literature:: With N,O-bis-(trimethylsilyl)-acetamide; MesP=CPhCMe₂(CNOCH(i-Pr)CMe₂)PdC₃H₅*OTf; potassium acetate; In dichloromethane; at 20 ℃; for 48h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ol1020652