Benzenamine, N-(1,2-dimethylpropylidene)-

Base Information

• Chemical Name: Benzenamine, N-(1,2-dimethylpropylidene)-
• CAS No.: 74265-71-7
• Molecular Formula: C11H15N
• Molecular Weight: 161.247
• DSSTox Substance ID: DTXSID60479278
• Nikkaji Number: J1.641.853F
• Mol file: 74265-71-7.mol

Synonyms:Benzenamine, N-(1,2-dimethylpropylidene)-;74265-71-7;SCHEMBL1037101;DTXSID60479278

Chemical Property of Benzenamine, N-(1,2-dimethylpropylidene)-

Chemical Property:

• XLogP3: 2.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 161.120449483
• Heavy Atom Count: 12
• Complexity: 152

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)C(=NC1=CC=CC=C1)C

Technology Process of Benzenamine, N-(1,2-dimethylpropylidene)-

There total 6 articles about Benzenamine, N-(1,2-dimethylpropylidene)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

2,3-dimethyl-2-(phenylamino)butanenitrile → N-phenyl-(1,2-dimethylpropylidene)amine (74265-71-7)

Guidance literature:

With potassium hydroxide; In methanol; for 1h; Reflux;

DOI:10.1002/jhet.2030

Reference yield: 39.0%

3-methyl-butan-2-one (563-80-4) + aniline (62-53-3) → N-phenyl-(1,2-dimethylpropylidene)amine (74265-71-7)

Guidance literature:

With 4 A molecular sieve; sodium hydrogencarbonate; In benzene; Heating;

DOI:10.1002/1521-3765(20020703)8:13<2955::AID-CHEM2955>3.0.CO;2-Q

Reference yield:

trimethylpyruvic acid (815-17-8) → N-phenyl-(1,2-dimethylpropylidene)amine (74265-71-7) + pivalaldehyde (630-19-3)

Guidance literature:

With aniline;

upstream raw materials:

3-methyl-butan-2-one

aniline

trimethylpyruvic acid

(N-phenyl)-1,2-dimethylpropanamamine

Downstream raw materials:

(1,2-Dimethyl-propyl)-phenyl-amine

N-phenyl-1,2-dimethylpropylamine

(N-phenyl)-1,2-dimethylpropanamamine

pivalaldehyde