Boroxin, tri-2-naphthalenyl-

Base Information

• Chemical Name: Boroxin, tri-2-naphthalenyl-
• CAS No.: 7519-88-2
• Molecular Formula: C30H21B3O3
• Molecular Weight: 461.928
• Mol file: 7519-88-2.mol

Synonyms:

Chemical Property of Boroxin, tri-2-naphthalenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Boroxin, tri-2-naphthalenyl-

There total 2 articles about Boroxin, tri-2-naphthalenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Triisopropyl borate (5419-55-6) + 2-naphthalenylmagnesium bromide (21473-01-8) → 2,4,6-tris-(2-naphthyl)boroxine (7519-88-2)

Guidance literature:

With sulfuric acid; water; byproducts: H2O; dehydration over H2SO4;;

Reference yield:

Trimethyl borate (121-43-7,63156-11-6) + 2-naphthalenylmagnesium bromide (21473-01-8) → 2,4,6-tris-(2-naphthyl)boroxine (7519-88-2)

Guidance literature:

With H₂O; H₂SO₄; byproducts: H2O; dehydration at 110°C;;

DOI:10.1039/j39660000566

Reference yield: 97.0%

C19H15NO4 + 2,4,6-tris-(2-naphthyl)boroxine (7519-88-2) → C29H23NO4 (1204518-57-9)

Guidance literature:

With C₅₂H₃₆F₈O₂Rh₂; In 1,4-dioxane; water; at 50 ℃; for 12h; optical yield given as %ee; enantioselective reaction;

DOI:10.1021/ja909642h

upstream raw materials:

Triisopropyl borate

2-naphthalenylmagnesium bromide

Trimethyl borate

Downstream raw materials:

(R_C)-3-(2-naphthyl)cyclohexan-1-one

2-(3-methylphenyl)naphthalene

C₂₉H₂₃NO₄

N-benzyl-3,4-dihydro-4-(2-naphthyl)quinolin-2(1H)-one