Bicyclo[2.2.1]heptane, 2-phenoxy-

Base Information

• Chemical Name: Bicyclo[2.2.1]heptane, 2-phenoxy-
• CAS No.: 75211-13-1
• Molecular Formula: C13H16O
• Molecular Weight: 188.269
• Mol file: 75211-13-1.mol

Synonyms:

Chemical Property of Bicyclo[2.2.1]heptane, 2-phenoxy-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Bicyclo[2.2.1]heptane, 2-phenoxy-

There total 11 articles about Bicyclo[2.2.1]heptane, 2-phenoxy- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

norborn-2-ene (498-66-8) + phenol (108-95-2,27073-41-2) → phenyl norbornyl ether (75211-13-1)

Guidance literature:

iron(III) trifluoromethanesulfonate; In dibutyl ether; at 80 ℃; for 20h; Product distribution / selectivity;

Reference yield: 97.0%

norbornene (498-66-8) + phenol (108-95-2,27073-41-2) → 2-exo-phenyloxybicyclo[2.2.1]heptane (50414-49-8,75211-13-1,50414-48-7)

Guidance literature:

With silver trifluoromethanesulfonate; In 1,2-dichloro-ethane; at 90 ℃; for 1h; Inert atmosphere;

DOI:10.1021/jo201631x

Reference yield: 95.0%

norborn-2-ene (498-66-8) + phenol (108-95-2,27073-41-2) → 2-exo-phenyloxybicyclo[2.2.1]heptane (50414-49-8,75211-13-1,50414-48-7)

Guidance literature:

With copper(II) bis(trifluoromethanesulfonate); In 1,4-dioxane; at 80 ℃; for 18h;

DOI:10.1039/b509933a

upstream raw materials:

norborn-2-ene

phenol

tetrahydrofuran

sodium phenoxide

Downstream raw materials:

Norborneol

phenol

exo-2-norbornanol