(1aR)-3,4,5,5a,6,6a-Hexahydro-5aβ,6α-dihydroxy-4,4,6aβ-trimethylcycloprop[f]indene-1aβ,2(1H)-dicarbaldehyde

Base Information

• Chemical Name: (1aR)-3,4,5,5a,6,6a-Hexahydro-5aβ,6α-dihydroxy-4,4,6aβ-trimethylcycloprop[f]indene-1aβ,2(1H)-dicarbaldehyde
• CAS No.: 114924-37-7
• Molecular Formula: C₁₅H₂₀O₄
• Molecular Weight: 264.321
• Mol file: 114924-37-7.mol

Synonyms:9a-Hydroxymerulidial

Chemical Property of (1aR)-3,4,5,5a,6,6a-Hexahydro-5aβ,6α-dihydroxy-4,4,6aβ-trimethylcycloprop[f]indene-1aβ,2(1H)-dicarbaldehyde

Chemical Property:

• Vapor Pressure: 4.56E-08mmHg at 25°C
• Boiling Point: 400.2°Cat760mmHg
• Flash Point: 210°C
• PSA: 74.60000
• Density: 1.29g/cm³
• LogP: 1.00280

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (1aR)-3,4,5,5a,6,6a-Hexahydro-5aβ,6α-dihydroxy-4,4,6aβ-trimethylcycloprop[f]indene-1aβ,2(1H)-dicarbaldehyde

There total 2 articles about (1aR)-3,4,5,5a,6,6a-Hexahydro-5aβ,6α-dihydroxy-4,4,6aβ-trimethylcycloprop[f]indene-1aβ,2(1H)-dicarbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 28.0%

Merulidial (68053-32-7) → (1aR,6aS)-1a,4,4-Trimethyl-2,6-dioxo-1a,2,3,4,5,6-hexahydro-1H-cyclopropa[f]indene-6a-carbaldehyde (108893-59-0) + (1aR,2R,2aS,6aR)-2,2a-Dihydroxy-1a,4,4-trimethyl-1a,2,2a,3,4,5-hexahydro-1H-cyclopropa[f]indene-6,6a-dicarbaldehyde (108893-58-9,114924-37-7)

Guidance literature:

With sodium acetate; pyridinium chlorochromate; In dichloromethane; Mechanism;

DOI:10.1016/S0040-4020(01)87324-5

Reference yield:

Merulidial (68053-32-7) → (3α,5α,6β)-6-hydroxy-5,9,9-trimethyl-2-oxotricyclo<5.3.0.03,5>-dec-1(7)-ene-3-carbaldehyde (114838-70-9) + 9α-hydroxymerulidial (114924-37-7)

Guidance literature:

With aluminum oxide; oxygen; In ethyl acetate; Petroleum ether;

Reference yield:

acetic anhydride (108-24-7) + 9α-hydroxymerulidial (114924-37-7) → 8-O-acetyl-9α-hydroxymerulidial (114838-69-6)

Guidance literature:

In pyridine;

upstream raw materials:

Merulidial

Downstream raw materials:

8-O-acetyl-9α-hydroxymerulidial

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