alpha-D-Glucofuranose, 1,2-O-(1-methylethylidene)-, tributanoate

Base Information

Chemical Name:alpha-D-Glucofuranose, 1,2-O-(1-methylethylidene)-, tributanoate
CAS No.:125161-49-1
Molecular Formula:C₂₁H₃₄O₉
Molecular Weight:430.496
Hs Code.:
DSSTox Substance ID:DTXSID60154679
Nikkaji Number:J473.666D
Wikidata:Q76279601
Mol file:125161-49-1.mol

Synonyms:BRN 6008582;alpha-D-Glucofuranose, 1,2-O-(1-methylethylidene)-, tributanoate;125161-49-1;1,2-O-(1-Methylethylidene)-alpha-D-glucofuranose tributanoate;Tri-O-butanyl-3,5,6 O-isopropylidene-1,2-alpha-D-glucofurannose [French];Tri-O-butanyl-3,5,6 O-isopropylidene-1,2-alpha-D-glucofurannose;DTXSID60154679;C21H34O9;C21-H34-O9;LS-71428;3-O,5-O,6-O-Tributyryl-1-O,2-O-isopropylidene-alpha-D-glucofuranose

Suppliers and Price of alpha-D-Glucofuranose, 1,2-O-(1-methylethylidene)-, tributanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of alpha-D-Glucofuranose, 1,2-O-(1-methylethylidene)-, tributanoate

Chemical Property:

Vapor Pressure:9.13E-10mmHg at 25°C
Boiling Point:490.5°Cat760mmHg
Flash Point:209.3°C
Density:1.17g/cm³
XLogP3:2.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:9
Rotatable Bond Count:14
Exact Mass:430.22028266
Heavy Atom Count:30
Complexity:603

Purity/Quality:: 98%min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCC(=O)OCC(C1C(C2C(O1)OC(O2)(C)C)OC(=O)CCC)OC(=O)CCC
Isomeric SMILES:CCCC(=O)OC[C@H]([C@@H]1[C@@H]([C@@H]2[C@H](O1)OC(O2)(C)C)OC(=O)CCC)OC(=O)CCC

Technology Process of alpha-D-Glucofuranose, 1,2-O-(1-methylethylidene)-, tributanoate

There total 2 articles about alpha-D-Glucofuranose, 1,2-O-(1-methylethylidene)-, tributanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 141-75-3
butyryl chloride

: 18549-40-1
1,2-O-isopropylidene-α-D-glucofuranose

: 125161-49-1
tri-O-butanoyl-3,5,6 O-isopropylidene-1,2 α-D-glucofurannose

Guidance literature:: With tri-n-propylamine; In chloroform; for 3h; Heating;
DOI:10.1016/0223-5234(89)90049-4

Reference yield:

: 582-52-5
1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

: 125161-49-1
tri-O-butanoyl-3,5,6 O-isopropylidene-1,2 α-D-glucofurannose

Guidance literature:: Multi-step reaction with 2 steps

1: 61 percent / Amberlist Wet 15 (H⁺) / propan-2-ol / 70 °C

2: 62 percent / tripropylamine / CHCl₃ / 3 h / Heating

With tri-n-propylamine; Amberlist Wet 15 (H⁺); In chloroform; isopropyl alcohol;
DOI:10.1016/0223-5234(89)90049-4