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Diacetone-d-Glucose manufacturer
Cas No: 582-52-5
USD $ 38.0-50.0 / Kilogram 1 Kilogram 1000 Kilogram/Month XINXIANG AURORA BIOTECHNOLOGY CO., LTD. Contact Supplier
582-52-5 Diacetone-d-Glucose
Cas No: 582-52-5
USD $ 100.0-600.0 / Gram 10 Gram 500 Metric Ton/Day GZ HONESTCHEM CO., LTD Contact Supplier
High purity Diacetone-D-glucose with high quality cas:582-52-5
Cas No: 582-52-5
USD $ 32.0-100.0 / Kilogram 1 Kilogram 99999 Kilogram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
High quality 1,2:5,6-Di-O-Isopropylidene-Alpha-D-Glucofuranose supplier in China
Cas No: 582-52-5
No Data 1 Metric Ton 30 Metric Ton/Month Simagchem Corporation Contact Supplier
Diacetone-D-glucose
Cas No: 582-52-5
USD $ 12.0-12.0 / Gram 10 Gram 500 Metric Ton/Year Jinan Finer Chemical Co., Ltd Contact Supplier
Diacetone-D-glucose CAS NO.582-52-5
Cas No: 582-52-5
USD $ 1.0-3.0 / Kilogram 1 Kilogram 10 Kilogram/Day Hebei yanxi chemical co.,LTD. Contact Supplier
Top quality Diacetone-D-glucose Powder price cas:582-52-5
Cas No: 582-52-5
USD $ 109.0-129.0 / Kilogram 1 Kilogram 55 Metric Ton/Month Xi'an Quanao Biotech Co., Ltd. Contact Supplier
Large Stock 99.0% 1,2:5,6-di-O-isopropylidene-A-D-gulose 582-52-5 Producer
Cas No: 582-52-5
USD $ 0.1-0.1 / Gram 1 Gram 100 Metric Ton/Year Xi'an Xszo Chem Co., Ltd. Contact Supplier
Diacetone-D-Glucose
Cas No: 582-52-5
USD $ 2.0-4.0 / Kilogram 1 Kilogram 50 Metric Ton/Day EAST CHEMSOURCES LIMITED Contact Supplier
Factory Supply 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
Cas No: 582-52-5
No Data 1 1 Ality Chemical Corporation Contact Supplier

582-52-5 Usage

Purification Methods

Diacetone-D-glucose crystallises from Et2O, (needles), pet ether or *C6H6 and sublimes in vacuo. It is soluble in 7 volumes of H2O and 200 volumes of pet ether at their boiling points. The solubility in H2O at 17.5o is 4.3%. It precipitates from aqueous solutions on basification with NaOH. [Schmid & Karrer Helv Chim Acta 32 1371 1949, Fischer & Rund Chem Ber 49 90, 93 1916, IR: Kuhn Anal Chem 22 276 1950, Beilstein 19/12 V 318.]

Chemical Properties

white to light yellow crystal powde
InChI:InChI=1/C12H20O6/c1-11(2)14-5-6(16-11)8-7(13)9-10(15-8)18-12(3,4)17-9/h6-10,13H,5H2,1-4H3/t6-,7+,8-,9-,10-/m1/s1

582-52-5 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
TCI America (D1949)  1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose  >97.0%(GC) 582-52-5 10g 150.00CNY Detail
TCI America (D1949)  1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose  >97.0%(GC) 582-52-5 25g 280.00CNY Detail
Alfa Aesar (A15568)  Diacetone-D-glucose, 98+%    582-52-5 25g 500.0CNY Detail
Alfa Aesar (A15568)  Diacetone-D-glucose, 98+%    582-52-5 100g 1574.0CNY Detail
Alfa Aesar (A15568)  Diacetone-D-glucose, 98+%    582-52-5 500g 6716.0CNY Detail

582-52-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Diacetone-d-Glucose

1.2 Other means of identification

Product number -
Other names 1,2_5,6-Diisopropylidene-.α.-D-glucofuranose

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:582-52-5 SDS

582-52-5Synthetic route

(3aR,5R,6S,6aR)-6-(allyloxy)-5-((R)-2,2-dimethyl[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydrofuro[2,3-d][1,3]dioxole

(3aR,5R,6S,6aR)-6-(allyloxy)-5-((R)-2,2-dimethyl[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydrofuro[2,3-d][1,3]dioxole

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
582-52-5

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

Conditions
ConditionsYield
With 1,3-dimethylbarbituric acid; tetrakis(triphenylphosphine) palladium(0) In methanol at 40℃;100%
With tetrakis(triphenylphosphine) palladium(0); p-toluene sulfinic acid In dichloromethane for 0.416667h; Ambient temperature;99%
With 1,3-dimethylbarbituric acid; Pd(PPh3) In tetrahydrofuran at 90℃; for 24h;99%
3-O-allyloxycarbonyl-1,2,5,6-di-O-isopropylidene-α-D-glucofuranose
153763-40-7

3-O-allyloxycarbonyl-1,2,5,6-di-O-isopropylidene-α-D-glucofuranose

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
582-52-5

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

Conditions
ConditionsYield
With aminomethyl resin-supported N-propylbarbituric acid; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 20℃;100%
With palladium diacetate; sodium azide; trisodium tris(3-sulfophenyl)phosphine In water; acetonitrile at 25℃; for 1h;71%
3-O-(2-azidomethyl)phenylacetyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
428500-97-4

3-O-(2-azidomethyl)phenylacetyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

A

1,4-dihydro-3(2H)-isoquinolinone
24331-94-0

1,4-dihydro-3(2H)-isoquinolinone

B

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
582-52-5

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

Conditions
ConditionsYield
With hydrogen; Lindlar's catalyst In methanol at 20℃; for 3h;A n/a
B 100%
3-O-benzyl-1,2-5,6-O-diisopropylidene-α-D-glucofuranose
18685-18-2

3-O-benzyl-1,2-5,6-O-diisopropylidene-α-D-glucofuranose

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
582-52-5

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

Conditions
ConditionsYield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane; water for 1h; Sealed tube; Irradiation;98%
With hydrogen; palladium on activated charcoal In various solvent(s) at 20℃; under 760 Torr; for 10h;90%
With 3,3-dimethyldioxirane In dichloromethane; acetone for 48h; Ambient temperature;87.3%
(3aR,5S,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole-6-carboxylic acid allyl ester

(3aR,5S,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole-6-carboxylic acid allyl ester

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
582-52-5

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); p-toluene sulfinic acid In dichloromethane for 0.5h; Ambient temperature;98%
3-O-acetyl-1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose
16713-80-7

3-O-acetyl-1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
582-52-5

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

Conditions
ConditionsYield
With methanol; potassium permanganate; trimethylsulphonium iodide at 25℃; under 760.051 Torr; chemoselective reaction;96%
acetylesterase from orange peel;75%
With sodium methylate In tetrahydrofuran for 6h;
D-Glucose
2280-44-6

D-Glucose

acetone
67-64-1

acetone

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
582-52-5

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

Conditions
ConditionsYield
With iodine96%
With phosphoric acid; zinc(II) chloride93%
vanadyl triflate In acetonitrile at 20℃; for 10h;89%
1,2:5,6-di-O-isopropylidene-3-O-methylprenyl-α-D-glucofuranose
753488-63-0

1,2:5,6-di-O-isopropylidene-3-O-methylprenyl-α-D-glucofuranose

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
582-52-5

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

Conditions
ConditionsYield
With (PhSO2)2; water In dichloromethane at 80℃;96%
D-glucose
50-99-7

D-glucose

acetone
67-64-1

acetone

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
582-52-5

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

Conditions
ConditionsYield
With phosphoric acid; zinc(II) chloride95%
With phosphoric acid; zinc(II) chloride for 30h; Ambient temperature;91%
With sulfuric acid Inert atmosphere;85%
(3aR,5R,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-6-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-2-iodo-nonyloxy)-tetrahydro-furo[2,3-d][1,3]dioxole

(3aR,5R,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-6-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-2-iodo-nonyloxy)-tetrahydro-furo[2,3-d][1,3]dioxole

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
582-52-5

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

Conditions
ConditionsYield
With ammonium chloride; zinc In ethanol for 0.25h; Heating;93%
1,2:5,6-di-O-isopropylidene-3-O-(3'-methyl-2'-butenyl)-α-D-glucofuranose
224317-43-5

1,2:5,6-di-O-isopropylidene-3-O-(3'-methyl-2'-butenyl)-α-D-glucofuranose

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
582-52-5

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

Conditions
ConditionsYield
With (PhSO2)2; water In dichloromethane at 80℃;93%
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane; water at 20℃; for 9h;65%
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane for 9h;65%
1,2:5,6-di-O-isopropylidene-3-O-(2-nitro)phenylacetyl-α-D-glucofuranose
1223405-87-5

1,2:5,6-di-O-isopropylidene-3-O-(2-nitro)phenylacetyl-α-D-glucofuranose

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
582-52-5

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

Conditions
ConditionsYield
With ammonium chloride; zinc In methanol at 20℃;93%
C17H32O7SSi

C17H32O7SSi

A

2-(trimethylsilyl)ethanesulfinamide

2-(trimethylsilyl)ethanesulfinamide

B

(-)-(S)-2-(trimethylsilyl)ethane sulfinamide

(-)-(S)-2-(trimethylsilyl)ethane sulfinamide

C

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
582-52-5

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

Conditions
ConditionsYield
Stage #1: C17H32O7SSi With lithium hexamethyldisilazane In tetrahydrofuran at -78℃; for 2.2h; Sealed tube; Inert atmosphere; Schlenk technique;
Stage #2: With silica gel In methanol at -78 - 23℃; for 1h; Inert atmosphere; Schlenk technique;
A n/a
B 65.9%
C 92.6%
1,2:5,6-di-O-isopropylidene-3-O-(allenyl)-α-D-glucofuranoside
142363-22-2

1,2:5,6-di-O-isopropylidene-3-O-(allenyl)-α-D-glucofuranoside

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
582-52-5

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

Conditions
ConditionsYield
With osmium(VIII) oxide; N-methyl-2-indolinone In acetone at 20℃; for 22h; Hydrolysis;92%

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