Silanol, (1,1-dimethylethyl)dimethyl-, benzoate

Base Information

• Chemical Name: Silanol, (1,1-dimethylethyl)dimethyl-, benzoate
• CAS No.: 75732-41-1
• Molecular Formula: C13H20O2Si
• Molecular Weight: 236.386
• Mol file: 75732-41-1.mol

Synonyms:Dimethyl-tert-butylsilyl benzoate;

Chemical Property of Silanol, (1,1-dimethylethyl)dimethyl-, benzoate

Chemical Property:

• PSA: 57.53000
• LogP: 3.36870

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Silanol, (1,1-dimethylethyl)dimethyl-, benzoate

There total 16 articles about Silanol, (1,1-dimethylethyl)dimethyl-, benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

tert-butyldimethylsilane (29681-57-0) + benzoic acid (65-85-0,8013-63-6) → tert-butyldimethylsilyl benzoate (75732-41-1)

Guidance literature:

With Cu(PPh₃)3Cl; In acetonitrile; at 80 ℃; for 6h;

DOI:10.1080/00397910701465669

Reference yield: 85.0%

allyl tert-butyldimethylsilane (74472-22-3) + benzoic acid (65-85-0,8013-63-6) → tert-butyldimethylsilyl benzoate (75732-41-1)

Guidance literature:

With chlorotriphenylphosphinegold(I); silver trifluoromethanesulfonate; In 1,2-dichloro-ethane; at 80 ℃; for 1h;

DOI:10.1246/bcsj.79.1146

Reference yield: 80.0%

ketene t-butyldimethylsilyl methyl acetal (77086-38-5) + benzoic acid (65-85-0,8013-63-6) → tert-butyldimethylsilyl benzoate (75732-41-1)

Guidance literature:

In acetonitrile; at 25 ℃; for 0.0833333h;

DOI:10.1055/s-1981-29478

upstream raw materials:

1,1,1,3,5,5,5-heptamethyltrisiloxan

O-Benzoyl-N-carbethoxy-N-(dimethyl-tert-butylsilyl)-hydroxylamine

Benzenecarboperoxoic acid 1-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-phenyl-propyl ester

Benzenecarboperoxoic acid 1-(tert-butyl-dimethyl-silanyloxy)-1-methyl-ethyl ester

Downstream raw materials:

Benzoyl bromide

tert-butyldimethyl(1-phenylvinyloxy)silane

Benzoyl isothiocyanate

benzoic acid