[([1,1'-Biphenyl]-4-yl)ethynyl](trimethyl)silane

Base Information

Chemical Name:[([1,1'-Biphenyl]-4-yl)ethynyl](trimethyl)silane
CAS No.:75867-42-4
Molecular Formula:C17H18Si
Molecular Weight:250.415
Hs Code.:
European Community (EC) Number:633-315-2
DSSTox Substance ID:DTXSID60503249
Nikkaji Number:J3.288.230G
Wikidata:Q82356915

Synonyms:Biphenyl-4-ylethynyl-trimethyl-silane;75867-42-4;[([1,1'-Biphenyl]-4-yl)ethynyl](trimethyl)silane;DTXSID60503249;MFCD22687016;([1,1'-biphenyl]-4-ylethynyl)trimethylsilane

Suppliers and Price of [([1,1'-Biphenyl]-4-yl)ethynyl](trimethyl)silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [([1,1'-Biphenyl]-4-yl)ethynyl](trimethyl)silane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:250.117777109
Heavy Atom Count:18
Complexity:311

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)C#CC1=CC=C(C=C1)C2=CC=CC=C2

Technology Process of [([1,1'-Biphenyl]-4-yl)ethynyl](trimethyl)silane

There total 1 articles about [([1,1'-Biphenyl]-4-yl)ethynyl](trimethyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 92-66-0
4-bromo-1,1'-biphenyl

: 78389-87-4
((trimethylsilyl)ethynyl)zinc(II) chloride

: 75867-42-4
([1,1'-biphenyl]-4-ylethynyl)trimethylsilane

Guidance literature:: With triphenylphosphine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In tetrahydrofuran; diethyl ether; hexane; at 75 ℃;
DOI:10.1016/S0040-4020(97)00977-0

Reference yield: 78.0%

: 1648787-32-9
C₁₂H₁₄N₂O

: 75867-42-4
([1,1'-biphenyl]-4-ylethynyl)trimethylsilane

: 4‐([1,1'‐biphenyl]‐4‐yl)‐1,5‐dimethyl‐5H‐pyrido[4,3‐b]indole

Guidance literature:: With silver hexafluoroantimonate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; In 2,2,2-trifluoroethanol; at 120 ℃; for 24h; regioselective reaction; Sealed tube; Schlenk technique;
DOI:10.1039/d0cc04740f

Reference yield: 68.0%

: 29540-84-9
4-chlorophenyl trifluoromethanesulfonate

: 75867-42-4
([1,1'-biphenyl]-4-ylethynyl)trimethylsilane

: 4-([1,1'-biphenyl]-4-ylethynyl)phenyl trifluoromethanesulfonate

Guidance literature:: With potassium fluoride; palladium diacetate; 3-(tert-butyl(phenyl)phosphaneyl)-2-cyclohexyl-1-methyl-1H-indole; In 1,4-dioxane; at 110 ℃; for 20h; chemoselective reaction; Schlenk technique; Sealed tube;
DOI:10.1021/acs.orglett.1c04138