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High purity 4-Bromobiphenyl TOP1 supplier in China
Cas No: 92-66-0
USD $ 123.0-123.0 / Kilogram 1 Kilogram 30 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
4-Bromobiphenyl 99% for OLED Materials
Cas No: 92-66-0
No Data 1 Gram 1 Metric Ton/Month Shanghai Siwei Chemical Co., Ltd Contact Supplier
High purity 92-66-0 4-Bromobiphenyl
Cas No: 92-66-0
USD $ 100.0-500.0 / Gram 1 Gram 99999 Gram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
High quality 4-Bromobi Pheny1 supplier in China
Cas No: 92-66-0
No Data No Data Metric Ton/Day Simagchem Corporation Contact Supplier
92-66-0 1,1'-Biphenyl,4-bromo-
Cas No: 92-66-0
USD $ 2.0-2.0 / Kilogram 1 Kilogram 100 Metric Ton/Year Hebei yanxi chemical co.,LTD. Contact Supplier
4-Bromobiphenyl
Cas No: 92-66-0
No Data 1 Kilogram 20 Metric Ton/Week Henan Allgreen Chemical Co.,Ltd Contact Supplier
N-(1-cyanocyclopentyl)benzamide
Cas No: 92-66-0
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
4-Bromobiphenyl
Cas No: 92-66-0
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
4-Bromobi pheny
Cas No: 92-66-0
USD $ 1.0-1.0 / Kilogram 1 Kilogram 1000 Metric Ton/Year Henan Sinotech Import&Export Corporation Contact Supplier
TIANFUCHEM--92-66-0--4-Bromobiphenyl factory price
Cas No: 92-66-0
USD $ 2000.0-2000.0 / Metric Ton 1 Metric Ton 1000 Metric Ton/Day Henan Tianfu Chemical Co., Ltd. Contact Supplier

92-66-0 Usage

General Description

Colorless crystals. Insoluble in water.

Uses

Intermediates of Liquid Crystals

Fire Hazard

4-Bromobiphenyl is combustible.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4-Bromobiphenyl may be sensitive to light. 4-Bromobiphenyl can react with oxidizing materials.

Purification Methods

Crystallise the biphenyl from abolute EtOH and dry it in vacuo.[Beilstein 5 IV 1819.]

Chemical Properties

White powder
InChI:InChI=1/C12H9Br/c13-12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9H

92-66-0 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (A12638)  4-Bromobiphenyl, 98+%    92-66-0 250g 3916.0CNY Detail
Alfa Aesar (A12638)  4-Bromobiphenyl, 98+%    92-66-0 50g 983.0CNY Detail
Alfa Aesar (A12638)  4-Bromobiphenyl, 98+%    92-66-0 10g 244.0CNY Detail

92-66-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-Bromobiphenyl

1.2 Other means of identification

Product number -
Other names 1-bromo-4-phenylbenzene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:92-66-0 SDS

92-66-0Synthetic route

C68H84N4Ni2

C68H84N4Ni2

chlorobenzene
108-90-7

chlorobenzene

A

(μ-Cl)2Ni2(1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)2

(μ-Cl)2Ni2(1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)2

B

(4,4'-dimethyl-1,1'-biphenyl)
613-33-2

(4,4'-dimethyl-1,1'-biphenyl)

C

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 21h;A 100%
B n/a
C n/a
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

phenylboronic acid
98-80-6

phenylboronic acid

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With sodium carbonate In 1-methyl-pyrrolidin-2-one at 100℃; for 6h; Suzuki-Miyaura Coupling; Inert atmosphere;99%
With potassium carbonate In water at 90℃; for 1h; Suzuki-Miyaura coupling; chemoselective reaction;98%
With potassium carbonate In ethanol; water at 80℃; for 0.583333h; Catalytic behavior; Suzuki-Miyaura Coupling;96%
4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With sodium nitrite In acetonitrile at 80℃; for 1h; Sealed tube;99%
With N-Bromosuccinimide In acetonitrile at 80℃; for 12h;98%
With tetrabutylammomium bromide; copper(ll) bromide In water at 100℃; Sealed tube;88%
With N-Bromosuccinimide; potassium acetate In acetonitrile at 50℃; for 4h;85%
sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

bis(4-bromophenyl)iodonium bromide
65826-67-7

bis(4-bromophenyl)iodonium bromide

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
palladium dichloride In water for 0.00555556h; Suzuki coupling; microwave irradiation;97%
for 0.0833333h; Suzuki coupling; microwave irradiation;94%
In water at 100℃; for 0.05h; Suzuki coupling reaction; microwave irradiation;91%
In water at 100℃; for 0.05h; Suzuki coupling; microwave irradiation;91%
1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

phenylboronic acid
98-80-6

phenylboronic acid

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With potassium carbonate In ethanol; water at 50℃; for 2.5h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;97%
With potassium carbonate In ethanol; water at 100℃; for 1.5h; Suzuki-Miyaura Coupling; Green chemistry;94%
With potassium carbonate In ethanol at 80℃; for 3h; Suzuki-Miyaura Coupling; Schlenk technique;92%
bromochlorobenzene
106-39-8

bromochlorobenzene

phenylboronic acid
98-80-6

phenylboronic acid

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With C84H60Cl6Fe3N6Pd3; triethylamine at 20℃; for 0.383333h;97%
With sodium carbonate In water at 80℃; for 4.5h; Catalytic behavior; Suzuki Coupling; Green chemistry;90%
With tetrabutylammomium bromide In ethanol; water at 90℃; for 0.666667h; Catalytic behavior; Suzuki Coupling; Inert atmosphere;84%
With potassium carbonate In ethanol; water at 50℃; for 12h; Catalytic behavior; Suzuki-Miyaura Coupling; Green chemistry;65%
bromochlorobenzene
106-39-8

bromochlorobenzene

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With sodium carbonate In water at 80℃; for 4.16667h; Catalytic behavior; Suzuki Coupling; Green chemistry;93%
sodium 4-bromobenzenesulfinate
34176-08-4

sodium 4-bromobenzenesulfinate

phenylboronic acid
98-80-6

phenylboronic acid

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With copper diacetate; palladium dichloride In dimethyl sulfoxide; acetonitrile at 90℃; for 2h;92%
iodobenzene
591-50-4

iodobenzene

4-Bromophenylboronic acid
5467-74-3

4-Bromophenylboronic acid

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With tetrabutylammomium bromide; nickel; sodium carbonate In ethanol at 80℃; for 6h; Suzuki-Miyaura reaction;91%
With potassium carbonate In N,N-dimethyl-formamide at 120℃; for 1h; Suzuki Coupling;85%
With aluminum oxide; potassium fluoride; palladium for 0.0333333h; Suzuki reaction; Heating; microwave irradiation;80%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

2-phenyl-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine
24341-81-9

2-phenyl-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; potassium tert-butylate; triphenylphosphine In tetrahydrofuran; toluene at 70℃; for 24h; Suzuki-Miyaura Coupling;91%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

tributylphenylstannane
960-16-7

tributylphenylstannane

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With copper(l) iodide; triphenyl-arsane; 1-butyl-3-methylimidazolium Tetrafluoroborate; bis(benzonitrile)palladium(II) dichloride at 80℃; for 18h; Stille coupling;90%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

triphenylindium
3958-47-2

triphenylindium

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride In tetrahydrofuran for 2h; Heating;90%
With 3-aminopropyl-functionalized silica supported MCM-41-immobilized palladium(0)-[(pyridin-2-yl)methylidene]amine complex In tetrahydrofuran at 68℃; for 2h; Inert atmosphere;87%
tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran Heating;
tributylphenylstannane
960-16-7

tributylphenylstannane

4-Bromobenzenediazonium o-benzenedisulfonimide

4-Bromobenzenediazonium o-benzenedisulfonimide

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
palladium diacetate In tetrahydrofuran at 20℃; for 1h; Stille reaction;90%
4-Bromophenylboronic acid
5467-74-3

4-Bromophenylboronic acid

benzenesufonyl hydrazide
80-17-1

benzenesufonyl hydrazide

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tert-butyl methyl ether at 60℃; for 6h; Suzuki Coupling;90%
4-Bromophenylboronic acid
5467-74-3

4-Bromophenylboronic acid

sodium benzenesulfonate
873-55-2

sodium benzenesulfonate

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With copper diacetate; palladium dichloride In dimethyl sulfoxide; acetonitrile at 90℃; for 2h;90%
p-bromodibenzoyl peroxide
1712-82-9

p-bromodibenzoyl peroxide

benzene
71-43-2

benzene

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
at 100℃; for 12h; Sealed tube;90%
trimethylphenylsilane
768-32-1

trimethylphenylsilane

4-bromobenzenediazonium tetrafluoroborate
673-40-5

4-bromobenzenediazonium tetrafluoroborate

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
With [bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) In acetonitrile at -78 - 20℃; Inert atmosphere; Irradiation;90%
o-benzenedisulfonimide
4482-01-3

o-benzenedisulfonimide

4-bromo-aniline
106-40-1

4-bromo-aniline

phenylboronic acid
98-80-6

phenylboronic acid

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

Conditions
ConditionsYield
Stage #1: o-benzenedisulfonimide; 4-bromo-aniline With acetic acid at 0 - 5℃; for 0.166667h; Inert atmosphere;
Stage #2: With isopentyl nitrite for 0.166667h; Inert atmosphere;
Stage #3: phenylboronic acid With bis[(trifluoromethanesulfonyl)imidate]-2-(dicyclohexyl(2’,6’-dimethoxybiphenyl))phosphine gold(I); caesium carbonate In tetrahydrofuran at 20℃; for 2h; Suzuki-Miyaura Coupling; Inert atmosphere; chemoselective reaction;
90%
4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

biphenyl
92-52-4

biphenyl

Conditions
ConditionsYield
With hydrogen In methanol at 20℃; for 24h;100%
Stage #1: 4-bromo-1,1'-biphenyl With n-butyllithium In tetrahydrofuran at -50℃; for 0.5h;
Stage #2: With phenylacetonitrile In tetrahydrofuran at -50 - 20℃; for 0.5h; Further stages;
99%
With [RhCl2(p-cymene)]2; potassium tert-butylate In isopropyl alcohol at 20 - 100℃; for 24h; Inert atmosphere;97%
4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

phenylboronic acid
98-80-6

phenylboronic acid

[1,1';4',1'']terphenyl
92-94-4

[1,1';4',1'']terphenyl

Conditions
ConditionsYield
With potassium phosphate; naphthidine di(radical cation)s-stabilized Pd nanoparticles In 1,4-dioxane at 80℃; for 5h; Suzuki-Miyaura cross-coupling reaction;100%
With potassium carbonate; [1,1'-bis{(S)-4-isopropyloxazolin-2-yl}ferrocene]Pd(II)Cl2 In toluene at 60℃; for 2h; Suzuki cross-coupling reaction;99%
With potassium phosphate; Pd (sulfur-containing palladacycle); tetra(n-tert-butyl)ammonium bromide In N,N-dimethyl-formamide at 130℃; for 2h; Suzuki cross-coupling;99%
4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

4-methoxy-phenol
150-76-5

4-methoxy-phenol

4-(4-methoxyphenoxy)-1,1'-biphenyl
40843-54-7

4-(4-methoxyphenoxy)-1,1'-biphenyl

Conditions
ConditionsYield
With copper(l) iodide; N,N-dimethylglycine hydrochoride; caesium carbonate In 1,4-dioxane at 90℃; for 18h; Product distribution / selectivity;100%
With copper(l) iodide; N,N-dimethylglycine hydrochoride; caesium carbonate In 1,4-dioxane at 90℃;91%
With silver(I) hexafluorophosphate; rhodium(II) acetate dimer; N,N-dicyclohexylbenzimidazolium hexafluorophosphate; sodium t-butanolate In toluene at 100℃; for 24h;60%
With potassium phosphate; (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile; [nickel(II) (4,4'-di-tert-butyl-2,2'-bipyridine)(bromide)2] at 25℃; for 36h; Schlenk technique; Inert atmosphere; Sealed tube; Irradiation;50%
4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

1,3-diphenylisobenzofuran
5471-63-6

1,3-diphenylisobenzofuran

2-phenyl-9,10-diphenyl-9,10-epoxyanthracene
1006715-11-2

2-phenyl-9,10-diphenyl-9,10-epoxyanthracene

Conditions
ConditionsYield
With Me2Zn(TMP)Li In tetrahydrofuran at 20℃; for 6h;100%
azetidine-3-ol
45347-82-8

azetidine-3-ol

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

1-biphenyl-4-yl-3-hydroxylcyclobutylamine
1380499-22-8

1-biphenyl-4-yl-3-hydroxylcyclobutylamine

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; CVT-2537 In dimethyl sulfoxide at 90℃; for 24h; Inert atmosphere;100%
4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

2-methyl-1,1’:4’,1’’-terphenyl
31158-32-4

2-methyl-1,1’:4’,1’’-terphenyl

Conditions
ConditionsYield
Stage #1: 2-Methylphenylboronic acid With potassium phosphate; 2C2F6NO4S2(1-)*C44H66Cl2N2P2Pd(2+); 1-butyl-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide In water at 65℃; Suzuki-Miyaura reaction; Inert atmosphere;
Stage #2: 4-bromo-1,1'-biphenyl In water at 65℃; for 2h; Suzuki-Miyaura reaction; Inert atmosphere;
99%
With potassium phosphate; water In toluene at 100℃; for 1h; Suzuki coupling reaction;85%
With potassium carbonate In ethanol; water at 70℃; for 14h; Suzuki coupling;70%
4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

tributyltin chloride
1461-22-9

tributyltin chloride

[1,1′-biphenyl]-4-yltributylstannane
51533-89-2

[1,1′-biphenyl]-4-yltributylstannane

Conditions
ConditionsYield
Stage #1: 4-bromo-1,1'-biphenyl With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h;
Stage #2: tributyltin chloride In tetrahydrofuran; hexane at -78℃; for 1h;
99%
With n-butyllithium In water78%
4,4-dimethylcyclohexenone
1073-13-8

4,4-dimethylcyclohexenone

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

4-(4,4-dimethylcyclohexa-1,5-dienyl)biphenyl
1263002-06-7

4-(4,4-dimethylcyclohexa-1,5-dienyl)biphenyl

Conditions
ConditionsYield
Stage #1: 4,4-dimethylcyclohexenone With tris-(dibenzylideneacetone)dipalladium(0); toluene-4-sulfonic acid hydrazide; lithium tert-butoxide; XPhos In 1,4-dioxane for 0.0166667h; Inert atmosphere;
Stage #2: 4-bromo-1,1'-biphenyl In 1,4-dioxane at 110℃; Inert atmosphere;
99%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

N,N,N,N,-tetramethylethylenediamine
110-18-9

N,N,N,N,-tetramethylethylenediamine

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

[(TMEDA)NiBr(C6H4Ph)]

[(TMEDA)NiBr(C6H4Ph)]

Conditions
ConditionsYield
In toluene at 23℃; for 2h;99%
potassium cyanate
590-28-3

potassium cyanate

carbon monoxide
201230-82-2

carbon monoxide

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

isopropyl alcohol
67-63-0

isopropyl alcohol

isopropyl biphenylcarbonylcarbamate

isopropyl biphenylcarbonylcarbamate

Conditions
ConditionsYield
With dichloro(1,5-cyclooctadiene)palladium(II); 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene at 70℃; for 8h;99%
2,2-dichloropropane
594-20-7

2,2-dichloropropane

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

dimethyl(4-biphenyl)silyl chloride
41081-31-6

dimethyl(4-biphenyl)silyl chloride

Conditions
ConditionsYield
Stage #1: 4-bromo-1,1'-biphenyl With n-butyllithium In diethyl ether; hexane at -78 - 20℃; for 3h; Schlenk technique; Glovebox;
Stage #2: 2,2-dichloropropane In diethyl ether; hexane at -78 - 20℃; for 15h; Schlenk technique; Glovebox;
99%

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