Technology Process of Acetic acid, [3-ethenyl-5-(phenylmethoxy)phenoxy]-, 1,1-dimethylethyl
ester
There total 8 articles about Acetic acid, [3-ethenyl-5-(phenylmethoxy)phenoxy]-, 1,1-dimethylethyl
ester which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Methyltriphenylphosphonium bromide;
With
potassium tert-butylate;
In
tetrahydrofuran;
for 0.333333h;
(3-benzyloxy-5-formyl-phenoxy)-acetic acid tert-butyl ester;
In
tetrahydrofuran;
at 20 ℃;
for 4h;
DOI:10.1021/ja047816a
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: 97 percent / K2CO3; NaI; 18-crown-6 / acetone / 36 h / Heating
2.1: 88 percent / pyridinium chlorochromate / CH2Cl2 / 3 h / 20 °C
3.1: KOtBu / tetrahydrofuran / 0.33 h
3.2: 87 percent / tetrahydrofuran / 4 h / 20 °C
With
18-crown-6 ether; potassium tert-butylate; potassium carbonate; pyridinium chlorochromate; sodium iodide;
In
tetrahydrofuran; dichloromethane; acetone;
DOI:10.1021/ja056042a
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: 36 percent / K2CO3; 18-crown-6 / acetone / 12 h / Heating
2.1: 89 percent / LiAlH4 / tetrahydrofuran / 12.5 h / 0 - 20 °C
3.1: 97 percent / K2CO3; NaI; 18-crown-6 / acetone / 36 h / Heating
4.1: 88 percent / pyridinium chlorochromate / CH2Cl2 / 3 h / 20 °C
5.1: KOtBu / tetrahydrofuran / 0.33 h
5.2: 87 percent / tetrahydrofuran / 4 h / 20 °C
With
lithium aluminium tetrahydride; 18-crown-6 ether; potassium tert-butylate; potassium carbonate; pyridinium chlorochromate; sodium iodide;
In
tetrahydrofuran; dichloromethane; acetone;
DOI:10.1021/ja056042a
