N-benzyl-2,2-dimethyl-6-methylsulfanyl-3H-thiopyran-4-imine;hydroiodide

Base Information

Chemical Name:N-benzyl-2,2-dimethyl-6-methylsulfanyl-3H-thiopyran-4-imine;hydroiodide
CAS No.:86795-66-6
Molecular Formula:C₁₅H₁₉NS₂*HI
Molecular Weight:405.367
Hs Code.:
DSSTox Substance ID:DTXSID80511245
NSC Number:382306

Synonyms:86795-66-6;DTXSID80511245;NSC382306;NSC-382306;(4Z)-N-Benzyl-2,2-dimethyl-6-(methylsulfanyl)-2,3-dihydro-4H-thiopyran-4-imine--hydrogen iodide (1/1)

Suppliers and Price of N-benzyl-2,2-dimethyl-6-methylsulfanyl-3H-thiopyran-4-imine;hydroiodide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of N-benzyl-2,2-dimethyl-6-methylsulfanyl-3H-thiopyran-4-imine;hydroiodide

Chemical Property:

Vapor Pressure:1.82E-05mmHg at 25°C
Boiling Point:374.3°Cat760mmHg
Flash Point:180.2°C
Density:1.09g/cm³
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:405.00819
Heavy Atom Count:19
Complexity:338

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(CC(=NCC2=CC=CC=C2)C=C(S1)SC)C.I

Technology Process of N-benzyl-2,2-dimethyl-6-methylsulfanyl-3H-thiopyran-4-imine;hydroiodide

There total 11 articles about N-benzyl-2,2-dimethyl-6-methylsulfanyl-3H-thiopyran-4-imine;hydroiodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 84260-81-1
6,6-Dimethyl-4-hydroxy-5,6-dihydro-2H-thiopyran-2-thion

: 86795-66-6
Benzyl-[2,2-dimethyl-6-methylsulfanyl-2,3-dihydro-thiopyran-(4Z)-ylidene]-amine; hydriodide

Guidance literature:: Multi-step reaction with 8 steps

1: 4.6 g / glacial CH₃COOH / benzene / 2 h / Heating

2: 1.3 g / 2N NaOH / H₂O / 16 h / 70 °C

3: 5.4 g / glacial CH₃COOH / benzene / 2 h / Heating

4: 1.5 g / 2N NaOH / H₂O / 16 h / 70 °C

5: 5.7 g / glacial CH₃COOH / benzene / 2 h / Heating

6: 1.4 g / 2N NaOH / H₂O / 16 h / 70 °C

7: 5.6 g / glacial CH₃COOH / benzene / 2 h / Heating

8: 4.0 g / CHCl₃ / 16 h

With sodium hydroxide; acetic acid; In chloroform; water; benzene;
DOI:10.1007/BF00808744

Reference yield:

: 76539-68-9
4-Diethylamino-6,6-dimethyl-5,6-dihydro-thiopyran-2-thione

: 86795-66-6
Benzyl-[2,2-dimethyl-6-methylsulfanyl-2,3-dihydro-thiopyran-(4Z)-ylidene]-amine; hydriodide

Guidance literature:: Multi-step reaction with 7 steps

1: 1.4 g / 2N NaOH / H₂O / 16 h / 70 °C

2: 4.6 g / glacial CH₃COOH / benzene / 2 h / Heating

3: 1.3 g / 2N NaOH / H₂O / 16 h / 70 °C

4: 5.4 g / glacial CH₃COOH / benzene / 2 h / Heating

5: 1.5 g / 2N NaOH / H₂O / 16 h / 70 °C

6: 5.6 g / glacial CH₃COOH / benzene / 2 h / Heating

7: 4.0 g / CHCl₃ / 16 h

With sodium hydroxide; acetic acid; In chloroform; water; benzene;
DOI:10.1007/BF00808744

Reference yield:

: 84260-84-4
4-Isobutylamino-6,6-dimethyl-5,6-dihydro-thiopyran-2-thione

: 86795-66-6
Benzyl-[2,2-dimethyl-6-methylsulfanyl-2,3-dihydro-thiopyran-(4Z)-ylidene]-amine; hydriodide

Guidance literature:: Multi-step reaction with 7 steps

1: 1.5 g / 2N NaOH / H₂O / 16 h / 70 °C

2: 4.6 g / glacial CH₃COOH / benzene / 2 h / Heating

3: 1.3 g / 2N NaOH / H₂O / 16 h / 70 °C

4: 5.7 g / glacial CH₃COOH / benzene / 2 h / Heating

5: 1.4 g / 2N NaOH / H₂O / 16 h / 70 °C

6: 5.6 g / glacial CH₃COOH / benzene / 2 h / Heating

7: 4.0 g / CHCl₃ / 16 h

With sodium hydroxide; acetic acid; In chloroform; water; benzene;
DOI:10.1007/BF00808744