Carbamodithioic acid, (1-methylethyl)(phenylmethyl)-, sodium salt

Base Information

• Chemical Name: Carbamodithioic acid, (1-methylethyl)(phenylmethyl)-, sodium salt
• CAS No.: 76300-70-4
• Molecular Formula: C11H15NS2.Na
• Molecular Weight: 247.361
• Mol file: 76300-70-4.mol

Synonyms:

Chemical Property of Carbamodithioic acid, (1-methylethyl)(phenylmethyl)-, sodium salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Carbamodithioic acid, (1-methylethyl)(phenylmethyl)-, sodium salt

There total 1 articles about Carbamodithioic acid, (1-methylethyl)(phenylmethyl)-, sodium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + Benzyl-isopropyl-amin (102-97-6) → sodium N-benzyl-N-isopropyldithiocarbamate trihydrate (76300-70-4)

Guidance literature:

With sodium hydroxide; In water; at 15 ℃; for 0.5h; Yield given;

Reference yield:

nickel(II) chloride hexahydrate + sodium N-benzyl-N-isopropyldithiocarbamate trihydrate (76300-70-4) → (benzylisopropyldithiocarbamate)2 nickel(II) (82421-76-9)

Guidance literature:

In water;

DOI:10.1080/00958972.2015.1107904

Reference yield:

di(4-t-butylphenyl)tindichloride (115030-90-5) + sodium N-benzyl-N-isopropyldithiocarbamate trihydrate (76300-70-4) → di-p-tert-butylphenyltin(IV)-bis-N,N-isopropyl-benzyldithiocarbamate (115030-82-5)

Guidance literature:

In acetone; byproducts: NaCl; addn. of Na-salt of dithiocarbamate to diorganotin dichloride; refluxing for 1h; filtration; removing solvent in vac.; dissolving solid residue in THF; pptn. (petroleum ether); elem. anal.;

upstream raw materials:

carbon disulfide

Benzyl-isopropyl-amin

Downstream raw materials:

di-p-tert-butylphenyltin(IV)-bis-N,N-isopropyl-benzyldithiocarbamate

bis(isopropyl benzyldithiocarbamato)bis(p-biphenyl)tin(IV)

tri-n-butyltin(IV)N-benzyl-N-isopropyldithiocarbamate

(benzylisopropyldithiocarbamate)2 nickel(II)

Refernces

• 1、 Masnovi, John,Duffy, Norman V.,Fanwick, Philip E.,Hepp, Aloysius F.. "Structural characterization and preliminary decomposition study of four unsymmetrically substituted nickel dithiocarbamate complexes". . p. 90 - 102. Retrieved 2016/01/20.
• 2、 Wadhwa, Sangeeta,Garg, B. S.,Sharma, C. P.,Kumar, N.. "Preparation and Characterization of Bis-Dithiocarbamato di-p-Tolyl Tin(IV)". . p. 247 - 250. Retrieved 2007/10/02.