Benzoic acid, 4-(4-pentenyloxy)-, 4-methoxyphenyl ester

Base Information

Chemical Name:Benzoic acid, 4-(4-pentenyloxy)-, 4-methoxyphenyl ester
CAS No.:76487-57-5
Molecular Formula:C19H20O4
Molecular Weight:312.365
Hs Code.:
DSSTox Substance ID:DTXSID90467042
Nikkaji Number:J906.103G
Wikidata:Q82293808

Synonyms:76487-57-5;Benzoic acid, 4-(4-pentenyloxy)-, 4-methoxyphenyl ester;SCHEMBL18763594;DTXSID90467042;4-Pent-4-enyloxy-benzoic acid 4-methoxy-phenyl ester

Suppliers and Price of Benzoic acid, 4-(4-pentenyloxy)-, 4-methoxyphenyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Benzoic acid, 4-(4-pentenyloxy)-, 4-methoxyphenyl ester

Chemical Property:

PSA：44.76000
LogP:4.25940
XLogP3:4.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:9
Exact Mass:312.13615911
Heavy Atom Count:23
Complexity:352

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=CC=C(C=C1)OC(=O)C2=CC=C(C=C2)OCCCC=C

Technology Process of Benzoic acid, 4-(4-pentenyloxy)-, 4-methoxyphenyl ester

There total 5 articles about Benzoic acid, 4-(4-pentenyloxy)-, 4-methoxyphenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1119-51-3
bromopentene

: 150-76-5
4-methoxy-phenol

: 99-76-3,156291-94-0
methyl 4-hydroxylbenzoate

: 76487-57-5
4'-methoxyphenyl 4-(pent-4''-enyloxy)benzoate

Guidance literature:: bromopentene; methyl 4-hydroxylbenzoate; With potassium carbonate; In 1-methyl-pyrrolidin-2-one; at 80 - 110 ℃; for 1.5h; Industrial scale;

With tetrabutylammomium bromide; sodium hydroxide; In 1-methyl-pyrrolidin-2-one; water; at 80 ℃; for 3h; Industrial scale;

4-methoxy-phenol; With dmap; 1,1'-carbonyldiimidazole; at 50 - 84 ℃; for 2.5h; Industrial scale;
DOI:10.1021/acs.oprd.6b00351

Reference yield: 56.0%

: 14142-82-6
4-(n-pent-4'-enyloxy)benzoic acid

: 150-76-5
4-methoxy-phenol

: 76487-57-5
4'-methoxyphenyl 4-(pent-4''-enyloxy)benzoate

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 24h; Inert atmosphere;
DOI:10.14233/ajchem.2016.19651

Reference yield:

: 120-47-8
Ethyl 4-hydroxybenzoate

: 76487-57-5
4'-methoxyphenyl 4-(pent-4''-enyloxy)benzoate

Guidance literature:: Multi-step reaction with 3 steps

1: potassium carbonate / butanone / 48 h / Reflux

2: sodium hydroxide; water / methanol / 3 h / Reflux

3: dicyclohexyl-carbodiimide; dmap / dichloromethane / 24 h / 20 °C / Inert atmosphere

With dmap; water; potassium carbonate; dicyclohexyl-carbodiimide; sodium hydroxide; In methanol; dichloromethane; butanone;
DOI:10.14233/ajchem.2016.19651