14142-82-6

Upstream product

• 14142-83-7 ethyl 4-(n-pent-4'-enyloxy)benzoate 
• 1119-51-3 bromopentene 
• 99-96-7 4-hydroxy-benzoic acid 
• 821-09-0 n-Pent-4-enyl alcohol 
• 19300-54-0 toluene-4-sulfonic acid pent-4-enyl ester 
• 120-47-8 Ethyl 4-hydroxybenzoate 
• 99-76-3 methyl 4-hydroxylbenzoate 
• 170458-46-5 methyl 4-(pent-4-en-1-yloxy)benzoate 

Downstream Products

• 142580-80-1 benzyl 4-(4-pentenyloxy)benzoate 
• 14142-84-8 5-pentenyloxybenzoic acid chloride 
• 188639-01-2 2-methyl-1,4-bis[4-(4-pentenyloxy)benzoyl]hydoquinone 
• 579501-27-2 2-oxo-7-(4-pent-4-enyloxy-benzoyloxy)-2H-chromene-3-carboxylic acid methyl ester 
• 579501-31-8 2-oxo-7-(4-pent-4-enyloxy-benzoyloxy)-2H-chromene-3-carboxylic acid pentyl ester 
• 579501-29-4 2-oxo-7-(4-pent-4-enyloxy-benzoyloxy)-2H-chromene-3-carboxylic acid propyl ester 
• 579501-30-7 2-oxo-7-(4-pent-4-enyloxy-benzoyloxy)-2H-chromene-3-carboxylic acid butyl ester 
• 579501-32-9 2-oxo-7-(4-pent-4-enyloxy-benzoyloxy)-2H-chromene-3-carboxylic acid hexyl ester 
• 579501-33-0 2-oxo-7-(4-pent-4-enyloxy-benzoyloxy)-2H-chromene-3-carboxylic acid heptyl ester 
• 579501-34-1 2-oxo-7-(4-pent-4-enyloxy-benzoyloxy)-2H-chromene-3-carboxylic acid octyl ester 
• 882053-70-5 C₅₀H₅₄O₈ 
• 521062-81-7 2-tert-butyl-1,4-bis[4-(4-pentenyloxy)benzoyl]hydroquinone 
• 1257226-85-9 2-(2,5-di(thiophen-2-yl)thiophen-3-yl)ethyl 4-(pent-4-enyloxy)benzoate 
• 76487-57-5 4'-methoxyphenyl 4-(pent-4''-enyloxy)benzoate 

Relevant academic research and scientific papers

Gas chromatographic and infrared studies of 4′-cyano-4-biphenyl 4-(4-pentenyloxy)benzoate coated on porous silica

The physical properties and the solute-surface interactions of porous silica modified with either the liquid crystal 4′-cyano-4-biphenyl 4-(4-pentenyloxy)benzoate (CBPB) or the structurally similar compound 4-biphenyl 4-(4-pentenyloxy)benzoate (BPB) have

Improved preparation of an epoxy substituted reactive mesogen

An improved manufacturing process was developed for the epoxy substituted mesogen 1 useful for the preparation of liquid crystalline materials. Notable features were telescoping of reactions, replacement of DCC with CDI for formation of a sensitive diaryl

Rhodium(III)-Catalyzed Synthesis of Skipped Enynes via C(sp3)–H Alkynylation of Terminal Alkenes

The RhIII-catalyzed allylic C?H alkynylation of non-activated terminal alkenes leads selectively to linear 1,4-enynes at room-temperature. The catalytic system tolerates a wide range of functional groups without competing functionalization at other positions. Similarly, the vinylic C?H alkynylation of α,β- and β,γ- unsaturated amides gives conjugated Z-1,3-enynes and E-enediynes.

Synthesis and characterization of liquid crystalline organosiloxanes containing 4-methoxyphenyl 4-(2-alkenyloxy)benzoate

A series of new organosiloxane liquid crystalline materials based on the 4-methoxyphenyl-4-(ù-alkenyloxy)benzoate as mesogenic units have been synthesized and their mesomorphic and physical properties have been characterized. A series of new disiloxanes and trisiloxanes contain 4-methoxyphenyl 4-(ù-alkenyloxy)benzoate as mesogenic these were synthesized by addition of 4-methoxyphenyl 4-(ù-alkenyloxy)benzoate moiety to pentamethylhydrodisiloxane or heptamethylhydrotrisiloxane catalyzed by platinum divinyltetramethyldisiloxane complex. The thermal properties of this new series of thermotropic liquid-crystalline siloxanes were studied by differential scanning calorimetry and polarized optical microscope. Disiloxane series compounds were not showed any liquid crystal phase. Trisiloxanes series compounds exhibited nematic liquid crystal phase. The siloxane molecule helped to reduce the melting temperature. The thermal properties of the new siloxane series exhibited a pronounced odd-even effect with the length of alkyl segment.

Surface-initiated ring-opening metathesis polymerization (SI-ROMP): Synthesis and electropolymerization of terthiophene-functionalized olefin peripheral dendrons

We report on the synthesis and electrodeposition of peripheral olefin dendrons with electropolymerizable focal point terthiophene units. These films were utilized for surface initiated ring-opening metathesis polymerization (SI-ROMP) of norbornene to form

SHAPE MEMORY MAIN-CHAIN SMECTIC-C ELASTOMERS

Shape memory main-chain smectic-C elastomers are described, as are methods for their preparation and monomers used in such methods. The elastomers are prepared by hydrosilylation of a reaction mixture including a liquid crystalline diene, a crosslinking agent, and a bis(silyl hydride) compound. The elastomers exhibit shape-memory properties and spontaneously reversible shape changes. They are useful for fabrication of shape memory articles including, for example, implantable medical devices, contact lenses, reversible embossing media, and Fresnel lenses.

Silicon-containing polyphilic bent-core molecules: The importance of nanosegregation for the development of chirality and polar order in liquid crystalline phases formed by Achiral molecules

Polyphilic molecules composed of a bent aromatic core, oligo(siloxane) units, and alkyl segments were synthesized, and the self-organization of these molecules was investigated. Most materials organize into polar smectic liquid crystalline phases. The swi

Ureido or carbamate derivatives of crown ethers and of silicon usable for preparing supports intended for the separation by chromatography of metal cations and of organic molecules comprising amine functional groups

The invention relates to ureido or carbamate derivatives of crown ethers and of silicon of formula: These derivatives can be grafted to silica gel for the purpose of obtaining supports for the chromatographic separation of cations or of molecules compris

Tailored phase transitions via mixed-mesogen liquid crystalline polymers with silicon-based spacers

Control over thermotropic phase behavior in low-Tg main-chain liquid crystalline polymers (LCPs) is desired for a variety of applications, including soft actuation when cross-linked. Here, we describe the synthesis of new silicon-based main-cha

Induction of smectic layering in nematic liquid crystals using immiscible components. 1. Laterally attached side-chain liquid crystalline poly(norbornene)s and their low molar mass analogs with hydrocarbon/fluorocarbon substituents

{5-[[[2',5'-Bis[(4''-(n-(perfluoroalkyl)alkoxy)benzoyl)oxy]benzyl]oxy ]carbonyl]bicyclo[2.2.1]hept-2-ene]s were polymerized by ring-opening metathesis polymerization in THF at 40°C using Mo(CHCMe2Ph)(N-2,6(i)Pr2Ph)(O(t)Bu)2/sub