Silane, (5-hexen-1-ynyloxy)tris(1-methylethyl)-

Base Information

• Chemical Name: Silane, (5-hexen-1-ynyloxy)tris(1-methylethyl)-
• CAS No.: 765906-78-3
• Molecular Formula: C15H28OSi
• Molecular Weight: 252.472
• DSSTox Substance ID: DTXSID30470631
• Mol file: 765906-78-3.mol

Synonyms:Silane, (5-hexen-1-ynyloxy)tris(1-methylethyl)-;765906-78-3;DTXSID30470631

Chemical Property of Silane, (5-hexen-1-ynyloxy)tris(1-methylethyl)-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 7
• Exact Mass: 252.190942047
• Heavy Atom Count: 17
• Complexity: 269

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)[Si](C(C)C)(C(C)C)OC#CCCC=C

Technology Process of Silane, (5-hexen-1-ynyloxy)tris(1-methylethyl)-

There total 1 articles about Silane, (5-hexen-1-ynyloxy)tris(1-methylethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

hex-1-en-5-yne (14548-31-3) + triisopropylsilyl trifluoromethanesulfonate (80522-42-5) → hex-5-en-1-ynyloxy-triisopropyl-silane (765906-78-3)

Guidance literature:

hex-1-en-5-yne; With lithium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃;

With lithium tert-butyl hydroperoxide; In tetrahydrofuran; toluene; at -78 - 0 ℃; for 2.5h;

triisopropylsilyl trifluoromethanesulfonate; In tetrahydrofuran; toluene; at 0 ℃; for 0.5h;

DOI:10.1021/ja046586x

Reference yield: 76.0%

hex-5-en-1-ynyloxy-triisopropyl-silane (765906-78-3) → cyclohexenone (930-68-7)

Guidance literature:

With methanesulfonic acid; In dichloromethane; at 20 ℃; for 1h;

DOI:10.1016/j.tet.2006.06.037

Reference yield: 70.0%

2-(1-methyl-(E)-1-butenyl)-2-(triisopropylsilyl)ketene (866006-57-7) + hex-5-en-1-ynyloxy-triisopropyl-silane (765906-78-3) → 6-ethyl-5-methyl-2-(3-butenyl)-3-(triisopropylsiloxy)phenol

Guidance literature:

hex-5-en-1-ynyloxy-triisopropyl-silane; With methyllithium; In tetrahydrofuran; diethyl ether; at 20 ℃;

2-(1-methyl-(E)-1-butenyl)-2-(triisopropylsilyl)ketene; In tetrahydrofuran; diethyl ether; at 20 ℃; Further stages.;

DOI:10.1016/j.tet.2007.10.113

upstream raw materials:

hex-1-en-5-yne

triisopropylsilyl trifluoromethanesulfonate

Downstream raw materials:

cyclohexenone