Dimethyl 1,2,3,6,7,8-hexahydro-as-indacene-4,5-dicarboxylate

Base Information

• Chemical Name: Dimethyl 1,2,3,6,7,8-hexahydro-as-indacene-4,5-dicarboxylate
• CAS No.: 51037-20-8
• Molecular Formula: C16H18O4
• Molecular Weight: 274.3117
• NSC Number: 140650
• DSSTox Substance ID: DTXSID50301034
• Wikidata: Q82044560
• Mol file: 51037-20-8.mol

Synonyms:dimethyl 1,2,3,6,7,8-hexahydro-as-indacene-4,5-dicarboxylate;51037-20-8;NSC140650;DTXSID50301034;1,2,3,6,7,8-hexahydro-as-indacene-4,5-dicarboxylic acid dimethyl ester;NSC-140650;dimethyl1,2,3,6,7,8-hexahydro-as-indacene-4,5-dicarboxylate

Chemical Property of Dimethyl 1,2,3,6,7,8-hexahydro-as-indacene-4,5-dicarboxylate

Chemical Property:

• Vapor Pressure: 3.98E-08mmHg at 25°C
• Boiling Point: 445.4°Cat760mmHg
• Flash Point: 228.3°C
• Density: 1.227g/cm³
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 274.12050905
• Heavy Atom Count: 20
• Complexity: 367

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC(=O)C1=C2CCCC2=C3CCCC3=C1C(=O)OC

Technology Process of Dimethyl 1,2,3,6,7,8-hexahydro-as-indacene-4,5-dicarboxylate

There total 4 articles about Dimethyl 1,2,3,6,7,8-hexahydro-as-indacene-4,5-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

dimethyl 1,2,3,3a,5a,6,7,8-octahydro-as-indacene-4,5-dicarboxylate (852713-76-9) → dimethyl 1,2,3,6,7,8-hexahydro-as-indacene-4,5-dicarboxylate (51037-20-8)

Guidance literature:

With dimethylsulfoxonium methylide; In dimethyl sulfoxide; at 20 ℃; for 4h;

DOI:10.1039/b502213d

Reference yield:

1,2,3,4,5,6,6a,8a-Octahydro-as-indacen-7,8-dicarbonsaeuremethylester (51037-08-2) → dimethyl 1,2,3,6,7,8-hexahydro-as-indacene-4,5-dicarboxylate (51037-20-8)

Guidance literature:

With bromine;

Reference yield:

bicyclopentyl-1,1'-diene (934-02-1) + dimethyl acetylenedicarboxylate (762-42-5) → dimethyl 1,2,3,6,7,8-hexahydro-as-indacene-4,5-dicarboxylate (51037-20-8)

Guidance literature:

DOI:10.1021/jo01362a026

upstream raw materials:

bicyclopentyl-1,1'-diene

dimethyl acetylenedicarboxylate

1,2,3,4,5,6,6a,8a-Octahydro-as-indacen-7,8-dicarbonsaeuremethylester

dimethyl 1,2,3,3a,5a,6,7,8-octahydro-as-indacene-4,5-dicarboxylate

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 51037-20-8 dimethyl 1,2,3,6,7,8-hexahydro-as-indacene-4,5-dicarboxylate

Send

Send

Metric Ton KG G Pound L ML

Send

Send