[(6E)-6-hydroxyimino-2,2-dimethyl-3a,6a-dihydrofuro[2,3-d][1,3]dioxol-5-yl]methyl benzoate

Base Information

• Chemical Name: [(6E)-6-hydroxyimino-2,2-dimethyl-3a,6a-dihydrofuro[2,3-d][1,3]dioxol-5-yl]methyl benzoate
• CAS No.: 29781-91-7
• Molecular Formula: C15H17 N O6
• Molecular Weight: 307.303
• NSC Number: 126579
• DSSTox Substance ID: DTXSID10419149
• Mol file: 29781-91-7.mol

Synonyms:NSC126579;29781-91-7;DTXSID10419149;NSC-126579

Chemical Property of [(6E)-6-hydroxyimino-2,2-dimethyl-3a,6a-dihydrofuro[2,3-d][1,3]dioxol-5-yl]methyl benzoate

Chemical Property:

• Vapor Pressure: 5.54E-09mmHg at 25°C
• Boiling Point: 452.7°Cat760mmHg
• Flash Point: 227.6°C
• Density: 1.41g/cm³
• XLogP3: 2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 4
• Exact Mass: 307.10558726
• Heavy Atom Count: 22
• Complexity: 457

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1(OC2C(O1)OC(C2=NO)COC(=O)C3=CC=CC=C3)C
• Isomeric SMILES: CC1(OC\2C(O1)OC(/C2=N\O)COC(=O)C3=CC=CC=C3)C

Technology Process of [(6E)-6-hydroxyimino-2,2-dimethyl-3a,6a-dihydrofuro[2,3-d][1,3]dioxol-5-yl]methyl benzoate

There total 2 articles about [(6E)-6-hydroxyimino-2,2-dimethyl-3a,6a-dihydrofuro[2,3-d][1,3]dioxol-5-yl]methyl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.4%

5-O-benzoyl-1,2-O-isopropylidene-α-D-ribofuranos-3-ulose (6698-46-0) → (E/Z)-5-O-Benzoyl-3-deoxy-3-hydroxyimino-1,2-O-isopropylidene-α-D-erythro-pentofuranose (29781-91-7)

Guidance literature:

With hydroxylamine hydrochloride; In pyridine; ethanol; for 1h; Heating;

DOI:10.1002/hlca.19860690521

Reference yield:

→ (E/Z)-5-O-Benzoyl-3-deoxy-3-hydroxyimino-1,2-O-isopropylidene-α-D-erythro-pentofuranose (29781-91-7)

Guidance literature:

Keton IV, NH2OH;

Reference yield: 89.0%

(E/Z)-5-O-Benzoyl-3-deoxy-3-hydroxyimino-1,2-O-isopropylidene-α-D-erythro-pentofuranose (29781-91-7) → O-benzoyl-5-desoxy-3-hydroxyamino-3-O-isopropylidene-1,2-α-D-ribofuranose (83905-12-8)

Guidance literature:

With sodium cyanoborohydride; In methanol; for 2h;

DOI:10.1002/hlca.19860690521

upstream raw materials:

5-O-benzoyl-1,2-O-isopropylidene-α-D-ribofuranos-3-ulose

Downstream raw materials:

3-amino-5-O-benzoyl-3-deoxy-1,2-O-isopropylidene-α-D-ribofuranose

O-benzoyl-5-desoxy-3-hydroxyamino-3-O-isopropylidene-1,2-α-D-ribofuranose

5-O-benzoyl-1,2-O-isopropylidene-3-deoxy-3-nitro-D-ribofuranose

5-O-benzoyl-1,2-O-isopropylidene-3-deoxy-3-nitro-D-xylofuranose

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 29781-91-7 [(6Z)-6-(hydroxyimino)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl]methyl benzoate (non-preferred name)

Send

Send

Metric Ton KG G Pound L ML

Send

Send