2,2'-[Methylenebis(oxy)]dianiline

Base Information

Chemical Name:2,2'-[Methylenebis(oxy)]dianiline
CAS No.:77804-73-0
Molecular Formula:C13H14N2O2
Molecular Weight:230.266
Hs Code.:
DSSTox Substance ID:DTXSID30553150
Wikidata:Q82433670

Synonyms:77804-73-0;2,2'-[Methylenebis(oxy)]dianiline;Benzenamine, 2,2'-[methylenebis(oxy)]bis-;2-[(2-aminophenoxy)methoxy]aniline;methylene-dioxyaniline;SCHEMBL8569016;DTXSID30553150

Suppliers and Price of 2,2'-[Methylenebis(oxy)]dianiline

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 2,2'-[Methylenebis(oxy)]dianiline

Chemical Property:

XLogP3:2.3
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:230.105527694
Heavy Atom Count:17
Complexity:204

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C(=C1)N)OCOC2=CC=CC=C2N

Technology Process of 2,2'-[Methylenebis(oxy)]dianiline

There total 3 articles about 2,2'-[Methylenebis(oxy)]dianiline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 56207-31-9
formaldehyde-[bis-(2-nitro-phenyl)-acetal]

: 77804-73-0
bis-(2-amino-phenoxy)-methane

Guidance literature:: With hydrazine hydrate; palladium on activated charcoal; In ethanol; for 2h; Heating;
DOI:10.1007/BF00475582

Reference yield:

: 88-75-5,78813-12-4
2-hydroxynitrobenzene

: 77804-73-0
bis-(2-amino-phenoxy)-methane

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / K₂CO₃ / dimethylformamide / 0.58 h / Heating

2: 62 percent / H₂ / 10percent Pd/C / tetrahydrofuran / 12 h / 90007.2 Torr

With hydrogen; potassium carbonate; palladium on activated charcoal; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1016/S0022-328X(96)06544-8

Reference yield:

: 824-39-5
sodium o-nitrophenate

: 77804-73-0
bis-(2-amino-phenoxy)-methane

Guidance literature:: Multi-step reaction with 2 steps

1: ethylene glycol / 150 °C

2: Raney nickel; ethanol / Hydrogenation

With ethanol; nickel; ethylene glycol;
DOI:10.1002/hlca.19580410633