824-39-5Relevant articles and documents
Catalytic applications of β-cyclodextrin/palladium nanoparticle thin film obtained from oil/water interface in the reduction of toxic nitrophenol compounds and the degradation of azo dyes
Zare Asadabadi, Azam,Hoseini, S. Jafar,Bahrami, Mehrangiz,Nabavizadeh, S. Masoud
, p. 6513 - 6522 (2019/05/10)
A supramolecular catalyst of Pd/β-cyclodextrin thin film is synthesized via a facile and one-pot procedure at an oil-water interface. Macrocyclic oligosaccharides of cyclodextrins with glucose units have a wide range of applications due to their hydrophobic and chiral interior. Due to the ability of this supramolecular catalyst to form inclusion complexes with small organic molecules, the as-synthesized catalyst was applied for the reduction of toxic nitroaromatic compounds (p, o, m-nitrophenol and 4-Cl-2-nitrophenol) and the degradation of harmful azo dyes (methyl orange and bismarck brown) with considerable results. This investigation illustrates the change of the catalyst properties in the presence of molecular receptors attached to the catalyst surface.
Synthesis and isolation of non-chromophore cage-rearranged silsesquioxanes from base-catalyzed reactions
Hanprasit, Sasikarn,Tungkijanansin, Nuttanee,Prompawilai, Arisa,Eangpayung, Supattra,Ervithayasuporn, Vuthichai
supporting information, p. 16117 - 16120 (2016/10/31)
The nucleophilicity of both ortho- and meta-nitrophenolate anions is strong enough to give substituted products, but their basicity also facilitates cage-rearrangement reactions in polyhedral oligomeric silsesquioxanes (POSS). Anions having a stronger basicity, but weaker nucleophilicity, such as CO32-, gave products only from cage-rearrangement, with the cage expansion products being isolable in multi-gram quantities using conventional column chromatography.
Nadimido-substituted cyclophosphazene
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, (2008/06/13)
Disclosed are nadimido-substituted cyclophosphazene derivatives and thermosets thereof. The thermosets are useful as high temperature, flame resistant matrices for composites and as metal adhesives.