3-Buten-2-ol, 1-(2-propenyloxy)-

Base Information

Chemical Name:3-Buten-2-ol, 1-(2-propenyloxy)-
CAS No.:78735-39-4
Molecular Formula:C7H12O2
Molecular Weight:128.171
Hs Code.:
DSSTox Substance ID:DTXSID90471008
Nikkaji Number:J1.694.007K

Synonyms:78735-39-4;3-Buten-2-ol, 1-(2-propenyloxy)-;SCHEMBL16006665;DTXSID90471008

Suppliers and Price of 3-Buten-2-ol, 1-(2-propenyloxy)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-Buten-2-ol, 1-(2-propenyloxy)-

Chemical Property:

PSA：29.46000
LogP:0.73590
XLogP3:0.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:5
Exact Mass:128.083729621
Heavy Atom Count:9
Complexity:88.9

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C=CCOCC(C=C)O

Technology Process of 3-Buten-2-ol, 1-(2-propenyloxy)-

There total 1 articles about 3-Buten-2-ol, 1-(2-propenyloxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 55207-76-6
2-(allyloxy)acetaldehyde

: 1826-67-1
vinyl magnesium bromide

: 78735-39-4
1-(allyloxy)butyl-3-ene-2-ol

Guidance literature:: In tetrahydrofuran; at -78 - 20 ℃;
DOI:10.1002/ejoc.201300672

Reference yield: 77.0%

: 76-83-5
trityl chloride

: 78735-39-4
1-(allyloxy)butyl-3-ene-2-ol

: (((1-(allyloxy)but-3-en-2-yl)oxy)methanetriyl)tribenzene

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene;

Reference yield:

: 78735-39-4
1-(allyloxy)butyl-3-ene-2-ol

: (2R,3R,4S,5R,6S)-6-(((3R,4R,5S)-4-hydroxy-5-(4-(pyrimidin-2 yl)-1H-1,2,3-triazol-1-yl)tetrahydro-2H-pyran-3-yl)thio)-2-(hydroxymethyl)-5-methoxy-4-(4-(3,4,5-trifluorophenyl)-1H-1,2,3-triazol-1-yl)tetrahydro-2H-pyran-3-ol

Guidance literature:: Multi-step reaction with 11 steps

1.1: 1,8-diazabicyclo[5.4.0]undec-7-ene

2.1: Hoveyda-Grubbs catalyst second generation / dichloromethane / 16 h / 20 °C

3.1: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 16 h / 0 - 20 °C / Inert atmosphere

3.2: 16 h / 80 °C / Sealed tube

4.1: carbon dioxide / methanol / 35 °C / 75007.5 Torr

5.1: pyridine / dichloromethane / 18 h / 20 °C / Inert atmosphere

6.1: formic acid / diethyl ether / 16 h / 20 °C

7.1: pyridine; trifluoromethylsulfonic anhydride / dichloromethane / 0.5 h / -10 °C

7.2: 1.5 h / -10 °C / Molecular sieve

8.1: sodium methylate / methanol; tetrahydrofuran / 0.25 h / -10 °C

9.1: tetra(n-butyl)ammonium hydrogensulfate; sodium carbonate / ethyl acetate / 2.5 h / 20 °C

10.1: copper(ll) sulfate pentahydrate; sodium L-ascorbate / N,N-dimethyl-formamide; water / 14 h / 20 °C / Inert atmosphere

11.1: sodium methylate / methanol; tetrahydrofuran / 1 h / 0 - 20 °C

With pyridine; formic acid; Hoveyda-Grubbs catalyst second generation; copper(ll) sulfate pentahydrate; trifluoromethylsulfonic anhydride; carbon dioxide; sodium methylate; tetra(n-butyl)ammonium hydrogensulfate; sodium hydrogencarbonate; sodium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; sodium L-ascorbate; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide;