Stannanecarbodithioic acid, tris(4-methylphenyl)-, methyl ester

Base Information

Chemical Name:Stannanecarbodithioic acid, tris(4-methylphenyl)-, methyl ester
CAS No.:79634-87-0
Molecular Formula:C₂₃H₂₄S₂Sn
Molecular Weight:483.286
Hs Code.:

Synonyms:

Suppliers and Price of Stannanecarbodithioic acid, tris(4-methylphenyl)-, methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of Stannanecarbodithioic acid, tris(4-methylphenyl)-, methyl ester

Chemical Property:

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Stannanecarbodithioic acid, tris(4-methylphenyl)-, methyl ester

There total 1 articles about Stannanecarbodithioic acid, tris(4-methylphenyl)-, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 75-15-0,12122-00-8
carbon disulfide

: (C₆H₄CH₃)3Sn^(1-)*Li⁽¹⁺⁾=(C₆H₄CH₃)3SnLi

: 74-88-4
methyl iodide

: 79634-87-0
methyl{tri(p-tolyl)stannane}dithiocarboxylate

Guidance literature:: In tetrahydrofuran; byproducts: LiI; to (CH3C6H5)3SnLi in THF dropped under stirring CS2 in slight excess, colour change to red brown with warming, after cooling addn. of CH3I in excess; column chromy. (silica gel/THF), solvent removed from the violet fraction, elem. anal.;

Reference yield: 42.0%

: 79634-87-0
methyl{tri(p-tolyl)stannane}dithiocarboxylate

: 36477-75-5
tungsten pentacarbonyl tetrahydrofuran

: 86921-08-6
W(CO)5((CH₃C₆H₄)3SnCS₂CH₃)

Guidance literature:: In tetrahydrofuran; react. of ester and metal carbonyl (excess) under N2 in the dark, 2h; reducing volume; chromy. (silica gel, THF/petroleum ether); evapn.; freezing in ethanol; crushing; vigorously stirring up to room temp.; filtration; washing (ethanol); drying; subliming off excess metal carbonyl; elem. anal.;

Reference yield: 31.0%

: 79634-87-0
methyl{tri(p-tolyl)stannane}dithiocarboxylate

: dicarbonyl(η(5)-cyclopentadienyl)manganese(THF)

: 86921-13-3
(C₅H₅)Mn(CO)2((CH₃C₆H₄)3SnCS₂CH₃)

Guidance literature:: In tetrahydrofuran; react. of ester and metal carbonyl (excess) under N2 in the dark, 2h; reducing volume; chromy. (silica gel, THF/petroleum ether); evapn.; freezing in methanol; crushing; vigorously stirring up to room temp.; filtration; washing (methanol); drying; subliming off excess metal carbonyl; elem. anal.;