2-Cyclohexen-1-one, 6-(1-methylethylidene)-

Base Information

Chemical Name:2-Cyclohexen-1-one, 6-(1-methylethylidene)-
CAS No.:79801-34-6
Molecular Formula:C9H12O
Molecular Weight:136.194
Hs Code.:
DSSTox Substance ID:DTXSID00470784
Nikkaji Number:J2.113.086I
Wikidata:Q82298957

Synonyms:79801-34-6;2-Cyclohexen-1-one, 6-(1-methylethylidene)-;SCHEMBL9226689;DTXSID00470784

Suppliers and Price of 2-Cyclohexen-1-one, 6-(1-methylethylidene)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of 2-Cyclohexen-1-one, 6-(1-methylethylidene)-

Chemical Property:

PSA：17.07000
LogP:2.24190
XLogP3:2.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:136.088815002
Heavy Atom Count:10
Complexity:205

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=C1CCC=CC1=O)C

Technology Process of 2-Cyclohexen-1-one, 6-(1-methylethylidene)-

There total 1 articles about 2-Cyclohexen-1-one, 6-(1-methylethylidene)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 485818-75-5
6-(1-hydroxy-1-methylethyl)cyclohex-2-en-1-one

: 79801-34-6
6-(1-methylethylidene)cyclohex-2-enone

Guidance literature:: With cerium(III) chloride; sodium iodide; In acetonitrile; for 2h; Heating;
DOI:10.1002/ejoc.200400419

Reference yield: 93.0%

: 73183-34-3
bis(pinacol)diborane

: 79801-34-6
6-(1-methylethylidene)cyclohex-2-enone

: 2-(propan-2-ylidene)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)cyclohexanone

Guidance literature:: With methanol; C₃₇H₃₅FeNP₂⁽¹⁺⁾; copper(l) chloride; sodium t-butanolate; In tetrahydrofuran; at 20 ℃; for 24h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1039/b914207j

Reference yield: 93.0%

: 73183-34-3
bis(pinacol)diborane

: 79801-34-6
6-(1-methylethylidene)cyclohex-2-enone

: (CH₃)2C(C₆H₇)(O)(pinacolatoboron)

Guidance literature:: With NaO(t-Bu); (R,S)-Taniaphos; CuCl; In methanol; tetrahydrofuran; CuCl (2 mol), NaO(t-Bu) (3 mol %), (R,S)-Taniaphos (4 mmol %), MeOH (2 equiv.), room temp., 24 h;
DOI:10.1039/b914207j