[3,3-Bis(4-methoxyphenyl)-2-phenylthiiran-2-yl](trimethyl)silane

Base Information

• Chemical Name: [3,3-Bis(4-methoxyphenyl)-2-phenylthiiran-2-yl](trimethyl)silane
• CAS No.: 79841-59-1
• Molecular Formula: C25H28O2SSi
• Molecular Weight: 420.648
• DSSTox Substance ID: DTXSID90507371
• Mol file: 79841-59-1.mol

Synonyms:79841-59-1;DTXSID90507371;[3,3-Bis(4-methoxyphenyl)-2-phenylthiiran-2-yl](trimethyl)silane

Chemical Property of [3,3-Bis(4-methoxyphenyl)-2-phenylthiiran-2-yl](trimethyl)silane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 6
• Exact Mass: 420.15792784
• Heavy Atom Count: 29
• Complexity: 516

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)C2(C(S2)(C3=CC=CC=C3)[Si](C)(C)C)C4=CC=C(C=C4)OC

Technology Process of [3,3-Bis(4-methoxyphenyl)-2-phenylthiiran-2-yl](trimethyl)silane

There total 1 articles about [3,3-Bis(4-methoxyphenyl)-2-phenylthiiran-2-yl](trimethyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

Bis(p-methoxyphenyl)diazomethan (1221-72-3) + trimethylsilyl phenyl thioketone (79841-55-7) → [3,3-Bis-(4-methoxy-phenyl)-2-phenyl-thiiranyl]-trimethyl-silane (79841-59-1)

Guidance literature:

In diethyl ether; Ambient temperature;

Reference yield: 100.0%

[3,3-Bis-(4-methoxy-phenyl)-2-phenyl-thiiranyl]-trimethyl-silane (79841-59-1) → [2,2-Bis-(4-methoxy-phenyl)-1-phenyl-vinyl]-trimethyl-silane (79841-64-8)

Guidance literature:

With triphenylphosphine; In benzene; for 4h; Heating;

Reference yield: 30.0%

[3,3-Bis-(4-methoxy-phenyl)-2-phenyl-thiiranyl]-trimethyl-silane (79841-59-1) → [(R)-3,3-Bis-(4-methoxy-phenyl)-1-oxo-2-phenyl-1λ4-thiiran-2-yl]-trimethyl-silane (89703-78-6) + C44H38O5S2 (89703-80-0)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -20 ℃;

DOI:10.1016/S0040-4039(00)99907-6

upstream raw materials:

Bis(p-methoxyphenyl)diazomethan

trimethylsilyl phenyl thioketone

Downstream raw materials:

[2,2-Bis-(4-methoxy-phenyl)-1-phenyl-vinyl]-trimethyl-silane

[(R)-3,3-Bis-(4-methoxy-phenyl)-1-oxo-2-phenyl-1λ⁴-thiiran-2-yl]-trimethyl-silane

C₄₄H₃₈O₅S₂

6-methoxy-3-(4-methoxyphenyl)-2-phenylbenzo[b]thiophene