79841-55-7

Upstream product

• 5908-41-8 benzoyltrimethylsilane 

Downstream Products

• 79841-59-1 [3,3-Bis-(4-methoxy-phenyl)-2-phenyl-thiiranyl]-trimethyl-silane 
• 105584-73-4 Trimethyl-(2-phenyl-3,3-di-p-tolyl-thiiranyl)-silane 
• 100181-21-3 3,6-diphenyl-6-trimethylsilyl-4H-1,5,2-oxathiazine 
• 117621-58-6 3-methyl-6-phenyl-2-(p-tolyl)imino-6-trimethylsilyl-5,6-dihydro-2H-thiopyran 
• 135275-83-1 2-Phenyl-2,6-bis-trimethylsilanyl-4H-[1,3]oxathiine 
• 105584-71-2 (E)-Phenyltrimethylsilyl thioketone S-oxide 
• 120800-97-7 2,4,6-Triphenyl-2,4,6-tris-trimethylsilanyl-[1,3,5]trithiane 
• 120851-48-1 (β)-2,4,6-triphenyl-2,4,6-tris(trimethyl-silyl)-1,3,5-trithiane 
• 79841-66-0 2,3,5-triphenyl-2-trimethylsilyl-2,3-dihydro-1,3,4-thiadiazole 
• 79841-68-2 2,5-diphenyl-5-trimethylsilyl-5H-1,4,2-oxathiazole 
• 79841-58-0 Trimethyl-(2,3,3-triphenyl-thiiranyl)-silane 
• 117621-56-4 2-isopropyl-6-methyl-4-phenyl-4-trimethylsilyl-4H-3,1-benzothiazine 
• 58-72-0 Triphenylethylene 
• 13187-62-7 2,4,5-triphenyl-Δ²-1,3,4-thiadiazoline 

Relevant academic research and scientific papers

Cobalt(II) Chloride Promoted Thionation of Carbonyl Compounds: A Simple Access to Silyl Thioketones and Thioaldehydes

The CoCl2-catalyzed reaction of Me3SiSSiMe3 with acylsilanes and simple aldehydes affords a direct and easy entry to their sulfur analogues.

Synthesis and Chemical Behaviour of Thioacylsilanes (Silyl Thioketones). Part 1. Oxidation to S-Oxides, Conversion into Silylated Thiiranes, Silylated Triarylethylenes, and α-Silylated Sulphides

Trimethylsilyl and triphenylsilylaryl thioketones have been synthesized by acid catalysed reaction of the corresponding ketones with hydrogen sulphide.Such silylated thioketones heve been oxidized to give S-oxides and converted with diaryldiazomethanes into triaryl thiiranes; upon treatment with organolithium nucleophiles they undergo thiophilic addition.The ready desulphurization with triphenylphosphine of silylated thiirans to the corresponding silyl triaryl ethylenes is also reported.

Silyl Thioketones and Silylated Thiirans

The preparation of silyl thioketones, and their reactions leading to silylated thiirans and other hitherto unknown silylated heterocycles, are reported.