2-Butynoic acid, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, ethyl ester

Base Information

Chemical Name:2-Butynoic acid, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, ethyl ester
CAS No.:80866-51-9
Molecular Formula:C12H22O3Si
Molecular Weight:242.39
Hs Code.:
DSSTox Substance ID:DTXSID90466212
Nikkaji Number:J1.362.023G
Wikidata:Q82292720

Synonyms:80866-51-9;2-Butynoic acid, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, ethyl ester;SCHEMBL221549;DTXSID90466212;UZWDBSNNFTYNHN-UHFFFAOYSA-N;Ethyl 4-(t-butyldimethylsilyloxy)-2-butynoate

Suppliers and Price of 2-Butynoic acid, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, ethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of 2-Butynoic acid, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, ethyl ester

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:5
Exact Mass:242.13382109
Heavy Atom Count:16
Complexity:301

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C#CCO[Si](C)(C)C(C)(C)C

Technology Process of 2-Butynoic acid, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, ethyl ester

There total 1 articles about 2-Butynoic acid, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 76782-82-6
tert-Butyldimethyl(prop-2-ynyloxy)silane

: 80866-51-9
ethyl 4-((tert-butyldimethylsilyl)oxy)but-2-ynoate

Guidance literature:

Reference yield: 89.0%

: 80866-51-9
ethyl 4-((tert-butyldimethylsilyl)oxy)but-2-ynoate

: 185990-03-8
dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane

: 1610597-86-8
(E)-ethyl 4-((tert-butyldimethylsilyl)oxy)-3-(dimethyl(phenyl)silyl)but-2-enoate

Guidance literature:: With picoline; copper(II) sulfate; In water; at 20 ℃; for 2h; diastereoselective reaction; Green chemistry;
DOI:10.1002/anie.201310695

Reference yield: 88.0%

: 766-77-8
Dimethylphenylsilane

: 80866-51-9
ethyl 4-((tert-butyldimethylsilyl)oxy)but-2-ynoate

: 1360896-15-6
ethyl (E)-4-(tert-butyldimethylsilyl)oxy-2-dimethyl(phenyl)silyl-2-butenoate

Guidance literature:: With bis(dibenzylideneacetone)-palladium⁽⁰⁾; tricyclohexylphosphine; In toluene; at 20 ℃; for 16h; optical yield given as %de; stereoselective reaction; Inert atmosphere;
DOI:10.1021/ol300279c