Benzene, [(10-undecenyloxy)methyl]-

Base Information

Chemical Name:Benzene, [(10-undecenyloxy)methyl]-
CAS No.:81518-75-4
Molecular Formula:C18H28O
Molecular Weight:260.42
Hs Code.:
DSSTox Substance ID:DTXSID40466242
Nikkaji Number:J1.102.637K

Synonyms:Benzene, [(10-undecenyloxy)methyl]-;81518-75-4;Undec-10-enyl-oxymethylbenzene;SCHEMBL1469764;DTXSID40466242;LMWYHLXLBPELFF-UHFFFAOYSA-N

Suppliers and Price of Benzene, [(10-undecenyloxy)methyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Benzene, [(10-undecenyloxy)methyl]-

Chemical Property:

XLogP3:6.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:12
Exact Mass:260.214015512
Heavy Atom Count:19
Complexity:194

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C=CCCCCCCCCCOCC1=CC=CC=C1

Technology Process of Benzene, [(10-undecenyloxy)methyl]-

There total 6 articles about Benzene, [(10-undecenyloxy)methyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1367875-29-3
(((6-bromoundec-10-en-1-yl)oxy)methyl)benzene

: 1043905-82-3
(((5-(2-methylcyclopentyl)pentyl)oxy)methyl)benzene

: 81518-75-4
((undec-10-en-1-yloxy)methyl)benzene

Guidance literature:: With 2,3,3,4,4,5-hexamethyl-2-hexanethiol; (1,3-dimethylimidazol-2-ylidene)borane; di-tert-butoxydiazene; In benzene; at 80 ℃; for 2h;
DOI:10.1021/ja300416f

Reference yield:

: 100-44-7
benzyl chloride

: 1043905-82-3
(((5-(2-methylcyclopentyl)pentyl)oxy)methyl)benzene

: 81518-75-4
((undec-10-en-1-yloxy)methyl)benzene

Guidance literature:: Multi-step reaction with 5 steps

1.1: sodium hydride / tetrahydrofuran / 2 h / Reflux

1.2: 20 °C

2.1: tetrabutylammomium bromide; sodium acetate; pyridinium chlorochromate / dichloromethane / 2 h / 20 °C / Molecular sieve

3.1: magnesium / diethyl ether / 2.5 h / 20 °C

3.2: 3 h / -78 - 0 °C

4.1: phosphorus tribromide / dichloromethane / 1 h / 0 °C

5.1: (1,3-dimethylimidazol-2-ylidene)borane; 2,3,3,4,4,5-hexamethyl-2-hexanethiol; di-tert-butoxydiazene / benzene / 2 h / 80 °C

With 2,3,3,4,4,5-hexamethyl-2-hexanethiol; (1,3-dimethylimidazol-2-ylidene)borane; di-tert-butoxydiazene; tetrabutylammomium bromide; sodium acetate; phosphorus tribromide; sodium hydride; magnesium; pyridinium chlorochromate; In tetrahydrofuran; diethyl ether; dichloromethane; benzene; 3.2: Grignard reaction;
DOI:10.1021/ja300416f

Reference yield:

: 1043905-72-1
11-(benzyloxy)undec-1-en-6-ol

: 1043905-82-3
(((5-(2-methylcyclopentyl)pentyl)oxy)methyl)benzene

: 81518-75-4
((undec-10-en-1-yloxy)methyl)benzene

Guidance literature:: Multi-step reaction with 2 steps

1: phosphorus tribromide / dichloromethane / 1 h / 0 °C

2: (1,3-dimethylimidazol-2-ylidene)borane; 2,3,3,4,4,5-hexamethyl-2-hexanethiol; di-tert-butoxydiazene / benzene / 2 h / 80 °C

With 2,3,3,4,4,5-hexamethyl-2-hexanethiol; (1,3-dimethylimidazol-2-ylidene)borane; di-tert-butoxydiazene; phosphorus tribromide; In dichloromethane; benzene;
DOI:10.1021/ja300416f