Technology Process of (((5-(2-methylcyclopentyl)pentyl)oxy)methyl)benzene
There total 7 articles about (((5-(2-methylcyclopentyl)pentyl)oxy)methyl)benzene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
2,2'-azobis(isobutyronitrile); 2-phenyl-1,2,4-triazol-3-ylidene borane;
In
benzene;
for 2h;
optical yield given as %de;
Reflux;
DOI:10.1021/ja804150k
- Guidance literature:
-
With
2,3,3,4,4,5-hexamethyl-2-hexanethiol; (1,3-dimethylimidazol-2-ylidene)borane; di-tert-butoxydiazene;
In
benzene;
at 80 ℃;
for 2h;
DOI:10.1021/ja300416f
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: sodium hydride / tetrahydrofuran / 2 h / Reflux
1.2: 20 °C
2.1: tetrabutylammomium bromide; sodium acetate; pyridinium chlorochromate / dichloromethane / 2 h / 20 °C / Molecular sieve
3.1: magnesium / diethyl ether / 2.5 h / 20 °C
3.2: 3 h / -78 - 0 °C
4.1: phosphorus tribromide / dichloromethane / 1 h / 0 °C
5.1: (1,3-dimethylimidazol-2-ylidene)borane; 2,3,3,4,4,5-hexamethyl-2-hexanethiol; di-tert-butoxydiazene / benzene / 2 h / 80 °C
With
2,3,3,4,4,5-hexamethyl-2-hexanethiol; (1,3-dimethylimidazol-2-ylidene)borane; di-tert-butoxydiazene; tetrabutylammomium bromide; sodium acetate; phosphorus tribromide; sodium hydride; magnesium; pyridinium chlorochromate;
In
tetrahydrofuran; diethyl ether; dichloromethane; benzene;
3.2: Grignard reaction;
DOI:10.1021/ja300416f
