(Z)-4,8-Dimethyl-3,7-nonadien-2-ol

Base Information

Chemical Name:(Z)-4,8-Dimethyl-3,7-nonadien-2-ol
CAS No.:81535-53-7
Molecular Formula:C11H20O
Molecular Weight:168.279
Hs Code.:
UNII:7K46Z8RCBM
Nikkaji Number:J1.980.387B
Wikidata:Q27268441

Synonyms:(Z)-4,8-Dimethyl-3,7-nonadien-2-ol;FEMA No. 4102, Z-;UNII-7K46Z8RCBM;7K46Z8RCBM;4,8-Dimethyl-3,7-nonadien-2-ol, (3Z)-;3,7-Nonadien-2-ol, 4,8-dimethyl-, (Z)-;3,7-Nonadien-2-ol, 4,8-dimethyl-, (3Z)-;81535-53-7;(+/-)-(Z)-4,8-Dimethyl-3,7-nonadien-2-ol;SCHEMBL1617090;(3Z)-4,8-dimethyl-3,7-nonadien-2-ol;Q27268441

Suppliers and Price of (Z)-4,8-Dimethyl-3,7-nonadien-2-ol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of (Z)-4,8-Dimethyl-3,7-nonadien-2-ol

Chemical Property:

XLogP3:3.3
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:4
Exact Mass:168.151415257
Heavy Atom Count:12
Complexity:173

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C=C(C)CCC=C(C)C)O
Isomeric SMILES:CC(/C=C(/C)\CCC=C(C)C)O

Technology Process of (Z)-4,8-Dimethyl-3,7-nonadien-2-ol

There total 8 articles about (Z)-4,8-Dimethyl-3,7-nonadien-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 853065-81-3
1-methylgeraniol

: 34562-09-9,67845-50-5,81535-53-7,129454-74-6,151221-80-6,151284-13-8
(S,E)-4,8-dimethylnona-3,7-dien-2-ol

Guidance literature:: 1-methylgeraniol; With titanium(IV) isopropylate; D-(-)-diisopropyl tartrate; In dichloromethane; at -20 ℃; for 0.5h; Inert atmosphere;

With tert.-butylhydroperoxide; In decane; dichloromethane; at -20 ℃; for 15h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ja303023n

Reference yield:

: 27539-94-2
(3E)-4,8-dimethylnona-3,7-dien-2-one

: 34562-09-9,67845-50-5,81535-53-7,129454-74-6,151221-80-6,151284-13-8
(S,E)-4,8-dimethylnona-3,7-dien-2-ol

: 1333113-75-9
(R,E)-4,8-dimethylnona-3,7-dien-2-ol

Guidance literature:: With borane N,N-diethylaniline complex; (S)-1-methyl-3,3-diphenyl-hexahydropyrrolo[1,2-c][1,3,2]oxazaborole; In tetrahydrofuran; toluene; at -20 ℃; for 8h; Overall yield = 97 %; Overall yield = 29.7 mg;
DOI:10.1021/jo400248y

Reference yield:

: 141-27-5,96680-15-8
3,7-dimethyl-2,6-octadienal

: 34562-09-9,67845-50-5,81535-53-7,129454-74-6,151221-80-6,151284-13-8
(S,E)-4,8-dimethylnona-3,7-dien-2-ol

Guidance literature:: Multi-step reaction with 2 steps

1.1: diethyl ether / 1.5 h / Inert atmosphere

2.1: titanium(IV) isopropylate; D-(-)-diisopropyl tartrate / dichloromethane / 0.5 h / -20 °C / Inert atmosphere

2.2: 15 h / -20 °C / Inert atmosphere

With titanium(IV) isopropylate; D-(-)-diisopropyl tartrate; In diethyl ether; dichloromethane;
DOI:10.1021/ja303023n