Methanone, [1-(9-borabicyclo[3.3.1]non-9-yl)-5-[[5-(4-methylbenzoyl)-1H-pyrrol-2-yl] phenylmethyl]-1H-pyrrol-2-yl](4-methylphenyl)-

Base Information

• Chemical Name: Methanone, [1-(9-borabicyclo[3.3.1]non-9-yl)-5-[[5-(4-methylbenzoyl)-1H-pyrrol-2-yl] phenylmethyl]-1H-pyrrol-2-yl](4-methylphenyl)-
• CAS No.: 816454-52-1
• Molecular Formula: C39H39BN2O2
• Molecular Weight: 578.562
• Mol file: 816454-52-1.mol

Synonyms:

Chemical Property of Methanone, [1-(9-borabicyclo[3.3.1]non-9-yl)-5-[[5-(4-methylbenzoyl)-1H-pyrrol-2-yl] phenylmethyl]-1H-pyrrol-2-yl](4-methylphenyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Methanone, [1-(9-borabicyclo[3.3.1]non-9-yl)-5-[[5-(4-methylbenzoyl)-1H-pyrrol-2-yl] phenylmethyl]-1H-pyrrol-2-yl](4-methylphenyl)-

There total 2 articles about Methanone, [1-(9-borabicyclo[3.3.1]non-9-yl)-5-[[5-(4-methylbenzoyl)-1H-pyrrol-2-yl] phenylmethyl]-1H-pyrrol-2-yl](4-methylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

4-methyl-benzoyl chloride (874-60-2) + 10-(9-borabicyclo[3.3.1]non-9-yl)-1-(4-methylbenzoyl)-5-phenyldipyrromethane (816454-48-5) → (1-(9-bora-bicyclo[3.3.1]non-9-yl)-5-{[5-(4-methyl-benzoyl)-1H-pyrrol-2-yl]-phenyl-methyl}-1H-pyrrol-2-yl)-p-tolyl-methanone (816454-52-1)

Guidance literature:

With 2-mesitylmagnesium bromide; In tetrahydrofuran; at 20 ℃; for 0.25h;

DOI:10.1021/jo048587d

Reference yield:

4-methyl-benzoyl chloride (874-60-2) → (1-(9-bora-bicyclo[3.3.1]non-9-yl)-5-{[5-(4-methyl-benzoyl)-1H-pyrrol-2-yl]-phenyl-methyl}-1H-pyrrol-2-yl)-p-tolyl-methanone (816454-52-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 96 percent / tetrahydrofuran / 0.5 h / 20 °C

2: 79 percent / mesitylmagnesium bromide / tetrahydrofuran / 0.25 h / 20 °C

With 2-mesitylmagnesium bromide; In tetrahydrofuran;

DOI:10.1021/jo048587d

Reference yield: 90.0%

(1-(9-bora-bicyclo[3.3.1]non-9-yl)-5-{[5-(4-methyl-benzoyl)-1H-pyrrol-2-yl]-phenyl-methyl}-1H-pyrrol-2-yl)-p-tolyl-methanone (816454-52-1) → 1,9-bis-(4-methylbenzoyl)-5-phenyldipyrromethane (171523-04-9)

Guidance literature:

With pentan-1-ol; In tetrahydrofuran; for 1h; Heating;

DOI:10.1021/jo048587d

upstream raw materials:

4-methyl-benzoyl chloride

10-(9-borabicyclo[3.3.1]non-9-yl)-1-(4-methylbenzoyl)-5-phenyldipyrromethane

Downstream raw materials:

1,9-bis-(4-methylbenzoyl)-5-phenyldipyrromethane

1,9-bis[α-hydroxy-α-(p-tolyl)methyl]-5-phenyldipyrromethane

5,15-bis-(4-methylphenyl)-10,20-diphenyl-porphyrin