4-[(Oxolan-2-yl)methyl]cyclohex-2-en-1-one

Base Information

Chemical Name:4-[(Oxolan-2-yl)methyl]cyclohex-2-en-1-one
CAS No.:81842-27-5
Molecular Formula:C₁₁H₁₆O₂
Molecular Weight:180.247
Hs Code.:
DSSTox Substance ID:DTXSID80528535

Synonyms:81842-27-5;4-[(Oxolan-2-yl)methyl]cyclohex-2-en-1-one;DTXSID80528535

Suppliers and Price of 4-[(Oxolan-2-yl)methyl]cyclohex-2-en-1-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of 4-[(Oxolan-2-yl)methyl]cyclohex-2-en-1-one

Chemical Property:

PSA：26.30000
LogP:2.09080
XLogP3:1.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:180.115029749
Heavy Atom Count:13
Complexity:220

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1CC(OC1)CC2CCC(=O)C=C2

Technology Process of 4-[(Oxolan-2-yl)methyl]cyclohex-2-en-1-one

There total 3 articles about 4-[(Oxolan-2-yl)methyl]cyclohex-2-en-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 5831-70-9
2-(iodomethyl)tetrahydrofuran

: 81842-27-5
4-(Tetrahydro-furan-2-ylmethyl)-cyclohex-2-enone

Guidance literature:: Multi-step reaction with 2 steps

1: 76 percent / NaH / dimethylformamide

2: 1.) 6percent Na/Hg, Na₂HPO₄, 2.) p-toluenesulfonic acid / 1.) methanol, room temp., 30 min, 2.) ethanol, reflux, 20 h

With disodium hydrogenphosphate; sodium amalgam; sodium hydride; toluene-4-sulfonic acid; In N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)86766-0

Reference yield:

: 81841-89-6
4,4-(ethylenedioxy)-1-(phenylsulfonyl)cyclohexene

: 81842-27-5
4-(Tetrahydro-furan-2-ylmethyl)-cyclohex-2-enone

Guidance literature:: Multi-step reaction with 2 steps

1: 76 percent / NaH / dimethylformamide

2: 1.) 6percent Na/Hg, Na₂HPO₄, 2.) p-toluenesulfonic acid / 1.) methanol, room temp., 30 min, 2.) ethanol, reflux, 20 h

With disodium hydrogenphosphate; sodium amalgam; sodium hydride; toluene-4-sulfonic acid; In N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)86766-0

Reference yield:

: 81841-97-6
6,6-(ethylenedioxy)-3-<(2-tetrahydrofuranyl)methyl>-3-(phenylsulfonyl)cyclohexene

: 81842-21-9
4-(Tetrahydro-furan-2-ylmethyl)-cyclohex-3-enone

: 81842-27-5
4-(Tetrahydro-furan-2-ylmethyl)-cyclohex-2-enone

Guidance literature:: With disodium hydrogenphosphate; sodium amalgam; toluene-4-sulfonic acid; Yield given. Multistep reaction. Yields of byproduct given; 1.) methanol, room temp., 30 min, 2.) ethanol, reflux, 20 h;
DOI:10.1016/S0040-4039(00)86766-0