Technology Process of Arsine, 1,6-hexanediylbis[diphenyl-
There total 1 articles about Arsine, 1,6-hexanediylbis[diphenyl- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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C6H5-AsBr-6-AsBr-C6H5, BrMg-C6H5, Ae.;
- Guidance literature:
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With
phthalic acid dimethyl ester;
In
ethanol;
byproducts: KCl; Pt-compd. and the ligand (in molar ratio 1:1) were placed in a round bottom flask, then abs. EtOH and DMP were added and the mixt. refluxed for24 h;; the mixt. was filtered and washed with water (3 portions), ethanol (2 portions), ether (2 portions) and dried under vacuum; elem.anal.;;
DOI:10.1016/S0020-1693(00)81399-7
- Guidance literature:
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In
acetone; toluene;
byproducts: KCl; Pt-compd. was dissolved in dry acetone and placed in a flat bottomed flask; the ligand (in molar ratio 1:1) dissolved in toluene was then added dropwise to a stirred salt soln. over a period of 30 min at room temp.;; the mixt. was filtered and the ppt. washed with toluene (3 portions); the acetone-toluene filtrate was then evapd. to dryness and the solid redissolved in toluene and filtered again to remove KCl; the soln. was evapd. to dryness ; the ppt. was dried;;
DOI:10.1016/S0020-1693(00)81399-7