2-Penten-1-ol, 5-(2-(((1,1-dimethylethyl)dimethylsilyl)oxy)cyclohexyl)-, methyl ester, (1alpha(Z),2beta)-

Base Information

Chemical Name:2-Penten-1-ol, 5-(2-(((1,1-dimethylethyl)dimethylsilyl)oxy)cyclohexyl)-, methyl ester, (1alpha(Z),2beta)-
CAS No.:101976-95-8
Molecular Formula:C₁₇H₃₄O₂Si
Molecular Weight:298.541
Hs Code.:

Synonyms:101976-95-8;2-Penten-1-ol, 5-(2-(((1,1-dimethylethyl)dimethylsilyl)oxy)cyclohexyl)-, methyl ester, (1alpha(Z),2beta)-

Suppliers and Price of 2-Penten-1-ol, 5-(2-(((1,1-dimethylethyl)dimethylsilyl)oxy)cyclohexyl)-, methyl ester, (1alpha(Z),2beta)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-Penten-1-ol, 5-(2-(((1,1-dimethylethyl)dimethylsilyl)oxy)cyclohexyl)-, methyl ester, (1alpha(Z),2beta)-

Chemical Property:

Vapor Pressure:2.38E-06mmHg at 25°C
Boiling Point:351.7°Cat760mmHg
Flash Point:166.5°C
Density:0.92g/cm³
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:7
Exact Mass:298.232806857
Heavy Atom Count:20
Complexity:305

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)OC1CCCCC1CCC=CCO
Isomeric SMILES:CC(C)(C)[Si](C)(C)O[C@H]1CCCC[C@@H]1CC/C=C\CO

Technology Process of 2-Penten-1-ol, 5-(2-(((1,1-dimethylethyl)dimethylsilyl)oxy)cyclohexyl)-, methyl ester, (1alpha(Z),2beta)-

There total 10 articles about 2-Penten-1-ol, 5-(2-(((1,1-dimethylethyl)dimethylsilyl)oxy)cyclohexyl)-, methyl ester, (1alpha(Z),2beta)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 101859-37-4,101976-93-6
(Z)-5-[(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-cyclohexyl]-pent-2-enoic acid methyl ester

: 101859-39-6,101976-95-8
(Z)-5-[(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-cyclohexyl]-pent-2-en-1-ol

Guidance literature:: With diisobutylaluminium hydride; In diethyl ether; at -78 - 0 ℃; Yield given;
DOI:10.1021/jo00362a014

Reference yield:

: 101859-37-4,101976-93-6
(E)-5-[(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-cyclohexyl]-pent-2-enoic acid methyl ester

: 101859-39-6,101976-95-8
(E)-5-[(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-cyclohexyl]-pent-2-en-1-ol

Guidance literature:: With diisobutylaluminium hydride; In diethyl ether; at -78 - 0 ℃; Yield given;
DOI:10.1021/jo00362a014

Reference yield:

: 286-20-4
cyclohexane-1,2-epoxide

: 101859-39-6,101976-95-8
(Z)-5-[(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-cyclohexyl]-pent-2-en-1-ol

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) CuI / 1.) Et₂O

2: 75 percent / TEA,DMAP / tetrahydrofuran; dimethylformamide / Heating

3: 1.) O₃, 2.) Me₂S / 1.) MeOH, - 60 deg C

4: 56 percent / KN(Me₄Si)2, 18-C-6 / tetrahydrofuran

5: dibal / diethyl ether / -78 - 0 °C

With dmap; copper(l) iodide; 18-crown-6 ether; dimethylsulfide; KN(Me₄Si)2; diisobutylaluminium hydride; ozone; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/jo00362a014