5,8-Quinolinedione, 6-[[(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)methyl]amino]-4-phenyl -

Base Information

Chemical Name:5,8-Quinolinedione, 6-[[(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)methyl]amino]-4-phenyl -
CAS No.:824405-26-7
Molecular Formula:C22H16N2O6
Molecular Weight:404.379
Hs Code.:

Synonyms:

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Chemical Property of 5,8-Quinolinedione, 6-[[(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)methyl]amino]-4-phenyl -

Chemical Property:

Purity/Quality:

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Hazard Codes:

MSDS Files:: SDS file from LookChem

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Technology Process of 5,8-Quinolinedione, 6-[[(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)methyl]amino]-4-phenyl -

There total 5 articles about 5,8-Quinolinedione, 6-[[(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)methyl]amino]-4-phenyl - which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 824405-24-5
6-amino-4-phenyl-quinoline-5,8-dione

: 2033-24-1
cycl-isopropylidene malonate

: 122-51-0
orthoformic acid triethyl ester

: 824405-26-7
6-[(2,2-dimethyl-4,6-dioxo-[1,3]dioxan-5-ylidenemethyl)-amino]-4-phenyl-quinoline-5,8-dione

Guidance literature:: cycl-isopropylidene malonate; orthoformic acid triethyl ester; for 2h; Heating;

6-amino-4-phenyl-quinoline-5,8-dione; for 4h; Heating;
DOI:10.1016/j.bmc.2004.09.021

Reference yield:

: 934-56-5
trimethyl(phenyl)stannane

: 824405-26-7
6-[(2,2-dimethyl-4,6-dioxo-[1,3]dioxan-5-ylidenemethyl)-amino]-4-phenyl-quinoline-5,8-dione

Guidance literature:: Multi-step reaction with 4 steps

1.1: copper(I) bromide; tetrakis(triphenylphosphine)palladium⁽⁰⁾ / dioxane / 1.5 h / 90 °C

2.1: ammonium cerium(IV) nitrate; sulfuric acid / acetonitrile / 3 h / 20 °C

3.1: 64 percent / sodium azide; hydrochloric acid / methanol; H₂O / 4 h / 20 °C / pH 4

4.1: 2 h / Heating

4.2: 76 percent / 4 h / Heating

With hydrogenchloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium azide; ammonium cerium(IV) nitrate; sulfuric acid; copper(I) bromide; In 1,4-dioxane; methanol; water; acetonitrile; 1.1: Stille coupling;
DOI:10.1016/j.bmc.2004.09.021

Reference yield:

: 114552-21-5
5,8-dimethoxy-4-trifluoromethansulfonyloxyquinoline

: 824405-26-7
6-[(2,2-dimethyl-4,6-dioxo-[1,3]dioxan-5-ylidenemethyl)-amino]-4-phenyl-quinoline-5,8-dione

Guidance literature:: Multi-step reaction with 4 steps

1.1: copper(I) bromide; tetrakis(triphenylphosphine)palladium⁽⁰⁾ / dioxane / 1.5 h / 90 °C

2.1: ammonium cerium(IV) nitrate; sulfuric acid / acetonitrile / 3 h / 20 °C

3.1: 64 percent / sodium azide; hydrochloric acid / methanol; H₂O / 4 h / 20 °C / pH 4

4.1: 2 h / Heating

4.2: 76 percent / 4 h / Heating

With hydrogenchloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium azide; ammonium cerium(IV) nitrate; sulfuric acid; copper(I) bromide; In 1,4-dioxane; methanol; water; acetonitrile; 1.1: Stille coupling;
DOI:10.1016/j.bmc.2004.09.021