Stannane, trimethylphenyl-

Base Information

• Chemical Name: Stannane, trimethylphenyl-
• CAS No.: 934-56-5
• Molecular Formula: C9H14 Sn
• Molecular Weight: 240.92
• Hs Code.: 2931900090
• European Community (EC) Number: 625-924-7
• DSSTox Substance ID: DTXSID60239415
• Wikidata: Q83121774
• Mol file: 934-56-5.mol

Synonyms:Trimethyl(phenyl)tin;Stannane, trimethylphenyl-;934-56-5;trimethyl(phenyl)stannane;Phenyltrimethyl tin;Trimethylphenylstannane;PHENYLTRIMETHYLTIN;Trimethylphenyltin;Phenyltrimethylstannane;trimethylphenyl tin;Trimethylmonophenyltin;Tin, trimethylphenyl-;Trimethylstannylbenzene;Trimethyl(phenyl)tin, 98%;DTXSID60239415;AKOS025293863;FT-0633140;J-525105;InChI=1/C6H5.3CH3.Sn/c1-2-4-6-5-3-1;/h1-5H;3*1H3

Chemical Property of Stannane, trimethylphenyl-

Chemical Property:

• Vapor Pressure: 0.338mmHg at 25°C
• Melting Point: −51 °C(lit.)
• Refractive Index: n20/D 1.5357(lit.)
• Boiling Point: 88 °C16 mm Hg(lit.)
• Flash Point: 76.1°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 2.23180
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 242.011753
• Heavy Atom Count: 10
• Complexity: 95.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Trimethylphenyltin ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T+,N
• Statements: 26/27/28-50/53
• Safety Statements: 26-27-28-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C[Sn](C)(C)C1=CC=CC=C1

Technology Process of Stannane, trimethylphenyl-

There total 69 articles about Stannane, trimethylphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

phenyltin trichloride (1124-19-2) → trimethyl(phenyl)stannane (934-56-5)

Guidance literature:

With methylmagnesium bromide; In diethyl ether;

DOI:10.1021/ic50006a047

Reference yield: 75.0%

trimethyltin bromide (1066-44-0) → trimethyl(phenyl)stannane (934-56-5)

Guidance literature:

With phenylmagnesium bromide; In diethyl ether; refluxing;;

Reference yield: 56.0%

phenyl(trimethylstannyl)methanone (120086-07-9) → trimethyl(phenyl)stannane (934-56-5)

Guidance literature:

bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; In toluene; byproducts: CO; reaction in the presence of 5 mol% of Ni(cod)2 at 100°C for 6.5 h;

DOI:10.1021/ja0020409

upstream raw materials:

trimethyltin bromide

bromobenzene

triethyl(phenyl)stannane

lithium trimethylstannyl

Downstream raw materials:

2-phenylbut-3-en-1-ol

(Z)-4-phenylbut-2-en-1-ol

(2E)-4-phenylbut-2-en-1-ol

(Z)-2-methyl-4-phenylbut-2-en-1-ol

Refernces

• 1、 Seyferth, Dietmar,Alleston, David L.. "The cleavage of hexamethyldisiloxane and hexamethyldigermoxane by methyllithium: A convenient preparation of lithium trimethylsilanolate and lithium trimethylgermanolate". . p. 418 - 420. Retrieved 1963.
• 2、 Lian, Chang,Yue, Guanglu,Mao, Jinshan,Liu, Danyang,Ding, Yi,Liu, Zerong,Qiu, Di,Zhao, Xia,Lu, Kui,Fagnoni, Maurizio,Protti, Stefano. "Visible-Light-Driven Synthesis of Arylstannanes from Arylazo Sulfones". supporting information. p. 5187 - 5191. Retrieved 2019/07/03.
• 3、 Lian, Chang,Yue, Guanglu,Zhang, Haonan,Wei, Liyan,Liu, Danyang,Liu, Sichen,Fang, Huayi,Qiu, Di. "Synthesis of arylstannanes by palladium-catalyzed desulfitative coupling reaction of sodium arylsulfinates with distannanes". supporting information. p. 4019 - 4023. Retrieved 2018/10/04.