Silver, chlorobis(triphenylphosphine)-

Base Information

Chemical Name:Silver, chlorobis(triphenylphosphine)-
CAS No.:82474-94-0
Molecular Formula:C36H30AgClP2
Molecular Weight:667.903
Hs Code.:

Synonyms:

Suppliers and Price of Silver, chlorobis(triphenylphosphine)-

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Silver, chlorobis(triphenylphosphine)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Silver, chlorobis(triphenylphosphine)-

There total 2 articles about Silver, chlorobis(triphenylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: silver(I) chloride

: 82474-94-0
(AgCl(PPh₃)2)

Guidance literature:: With triphenylphosphine; In chloroform; AgCl was suspended in chloroform and with stirring soln. of PPh3, chloroform was added dropwise, mixt. was stirred for 1 h at room temp.; filtered, pentane was added, cooled, filtered off, washed with pentane,dried in vac.; elem. anal.;
DOI:10.1016/S0020-1693(00)87331-4

Reference yield:

: 603-35-0
triphenylphosphine

: silver(I) chloride

: 82474-94-0
(AgCl(PPh₃)2)

Guidance literature:: In chloroform; at 20 ℃; for 4h; Inert atmosphere; Schlenk technique;
DOI:10.1002/ejic.201700115

Reference yield: 87.0%

: 82474-94-0
Ag(PPh₃)2Cl

: 4-(trimethylammonio)benzene thiolate hexafluorophosphate

: 690957-64-3
[Ag(4-(trimethylammonio)benzenethiolate)2]PF₆

: 111267-04-0
tetrakis(triphenylphosphine)silver hexafluorophosphate

Guidance literature:: With Et₃N; In methanol; dichloromethane; byproducts: HNEt3PF6, HnEt3Cl; to a suspn. of a ligand (0.21 mmol) in CH3OH was added Et3N; the soln. was then treated with a soln. of Ag-contg. compd. (0.20 mmol) in CH2Cl2; the mixt. was refluxed on an oil bath for 0.5 h; the ppt. was filtered off and the filtrate was cooled down to 5°C; the solid was redissolved in CH3CN; diethyl ether was allowed to diffuse into the CH3CN soln.; the crystals were washed with CH2Cl2/Et2O (1:4)and dried in vac.; elem. anal.;
DOI:10.1016/j.jorganchem.2004.01.016