tetrakis(triphenylphosphine)silver hexafluorophosphate

Base Information

• Chemical Name: tetrakis(triphenylphosphine)silver hexafluorophosphate
• CAS No.: 111267-04-0
• Molecular Formula: C₇₂H₆₀AgP₄*F₆P
• Molecular Weight: 1302
• Mol file: 111267-04-0.mol

Synonyms:tetrakis(triphenylphosphine)silver hexafluorophosphate

Chemical Property of tetrakis(triphenylphosphine)silver hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of tetrakis(triphenylphosphine)silver hexafluorophosphate

There total 4 articles about tetrakis(triphenylphosphine)silver hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

Ag(PPh3)2Cl (82474-94-0) + 4-(trimethylammonio)benzene thiolate hexafluorophosphate → [Ag(4-(trimethylammonio)benzenethiolate)2]PF6 (690957-64-3) + tetrakis(triphenylphosphine)silver hexafluorophosphate (111267-04-0)

Guidance literature:

With Et₃N; In methanol; dichloromethane; byproducts: HNEt3PF6, HnEt3Cl; to a suspn. of a ligand (0.21 mmol) in CH3OH was added Et3N; the soln. was then treated with a soln. of Ag-contg. compd. (0.20 mmol) in CH2Cl2; the mixt. was refluxed on an oil bath for 0.5 h; the ppt. was filtered off and the filtrate was cooled down to 5°C; the solid was redissolved in CH3CN; diethyl ether was allowed to diffuse into the CH3CN soln.; the crystals were washed with CH2Cl2/Et2O (1:4)and dried in vac.; elem. anal.;

DOI:10.1016/j.jorganchem.2004.01.016

Reference yield: 86.0%

silver(I) hexafluorophosphate (26042-63-7) → tetrakis(triphenylphosphine)silver hexafluorophosphate (111267-04-0)

Guidance literature:

With triphenyl phosphine; In acetonitrile; PPh3 was added to a soln. of AgPF6 in hot MeCN; elem. anal.;

Reference yield:

silver fluoride (11113-87-4) → tetrakis(triphenylphosphine)silver hexafluorophosphate (111267-04-0)

Guidance literature:

With triphenyl phosphine; In hydrogen fluoride; acetonitrile; aq. HF; aqueous HF was added to a soln. of AgF and PPh3 in boiling MeCN; cooling;

upstream raw materials:

silver(I) hexafluorophosphate

triphenylphosphine

Ag(PPh₃)2Cl

silver fluoride