Benzoic acid, 4-methoxy-, (2S,3R)-4-(diethoxyphosphinyl)-2,3-dihydroxybutyl ester

Base Information

Chemical Name:Benzoic acid, 4-methoxy-, (2S,3R)-4-(diethoxyphosphinyl)-2,3-dihydroxybutyl ester
CAS No.:828268-15-1
Molecular Formula:C16H25O8P
Molecular Weight:376.33900
Hs Code.:

Synonyms:4-Methoxy-benzoic acid (2S,3R)-4-(diethoxy-phosphoryl)-2,3-dihydroxy-butyl ester;

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzoic acid, 4-methoxy-, (2S,3R)-4-(diethoxyphosphinyl)-2,3-dihydroxybutyl ester

Chemical Property:

Boiling Point:546.0±50.0 °C(Predicted)
PSA：121.33000
Density:1.256±0.06 g/cm3(Predicted)
LogP:1.83990

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Benzoic acid, 4-methoxy-, (2S,3R)-4-(diethoxyphosphinyl)-2,3-dihydroxybutyl ester

There total 2 articles about Benzoic acid, 4-methoxy-, (2S,3R)-4-(diethoxyphosphinyl)-2,3-dihydroxybutyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 828268-13-9
(2E)-4-(diethoxyphosphoryl)but-2-enyl 4-methoxybenzoate

: 828268-15-1
(2S,3R)-4-(diethoxyphosphoryl)-2,3-dihydroxybutyl 4-methoxybenzoate

Guidance literature:: With potassium osmate(VI); AD-mix-α; methanesulfonamide; In tert-butyl alcohol; at 0 - 25 ℃; for 8h;
DOI:10.1055/s-2004-834792

Reference yield:

: 4-Methoxy-benzoic acid (E)-4-bromo-but-2-enyl ester

: 828268-15-1
(2S,3R)-4-(diethoxyphosphoryl)-2,3-dihydroxybutyl 4-methoxybenzoate

Guidance literature:: Multi-step reaction with 2 steps

1: 76 percent / acetone; acetonitrile / 12 h / 160 °C

2: AD-mix-α; K2OsO4*2H2O; MeSO2NH2 / H2O; 2-methyl-propan-2-ol / 6 h / 20 °C

With potassium osmate(VI); AD-mix-α; methanesulfonamide; In water; acetone; acetonitrile; tert-butyl alcohol; 1: Arbuzov reaction;
DOI:10.1016/j.tet.2005.09.126