2-Cyclohexen-1-ol, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-6-[2-(dimethylphenylsilyl)ethyl]-2- [(1S)-1-methyl-4-(triphenylmethoxy)butyl]-3-[(triphenylmethoxy)methyl]-, (1R,5R,6S)-

Base Information

Chemical Name:2-Cyclohexen-1-ol, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-6-[2-(dimethylphenylsilyl)ethyl]-2- [(1S)-1-methyl-4-(triphenylmethoxy)butyl]-3-[(triphenylmethoxy)methyl]-, (1R,5R,6S)-
CAS No.:828915-89-5
Molecular Formula:C66H78O4Si2
Molecular Weight:991.514
Hs Code.:

2-Cyclohexen-1-ol,
5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-6-[2-(dimethylphenylsilyl)ethyl]-2-
[(1S)-1-methyl-4-(triphenylmethoxy)butyl]-3-[(triphenylmethoxy)methyl]-,
(1R,5R,6S)-

Synonyms:

Suppliers and Price of 2-Cyclohexen-1-ol, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-6-[2-(dimethylphenylsilyl)ethyl]-2- [(1S)-1-methyl-4-(triphenylmethoxy)butyl]-3-[(triphenylmethoxy)methyl]-, (1R,5R,6S)-

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-Cyclohexen-1-ol, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-6-[2-(dimethylphenylsilyl)ethyl]-2- [(1S)-1-methyl-4-(triphenylmethoxy)butyl]-3-[(triphenylmethoxy)methyl]-, (1R,5R,6S)-

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2-Cyclohexen-1-ol, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-6-[2-(dimethylphenylsilyl)ethyl]-2- [(1S)-1-methyl-4-(triphenylmethoxy)butyl]-3-[(triphenylmethoxy)methyl]-, (1R,5R,6S)-

There total 3 articles about 2-Cyclohexen-1-ol, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-6-[2-(dimethylphenylsilyl)ethyl]-2- [(1S)-1-methyl-4-(triphenylmethoxy)butyl]-3-[(triphenylmethoxy)methyl]-, (1R,5R,6S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 76-83-5
trityl chloride

: 828915-88-4
(1R,5R,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[2-(dimethyl-phenyl-silanyl)-ethyl]-3-hydroxymethyl-2-((S)-4-hydroxy-1-methyl-butyl)-cyclohex-2-enol

: 828915-89-5
(1R,5R,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[2-(dimethyl-phenyl-silanyl)-ethyl]-2-((S)-1-methyl-4-trityloxy-butyl)-3-trityloxymethyl-cyclohex-2-enol

Guidance literature:: With pyridine; dmap; In dichloromethane; at 20 ℃;
DOI:10.1002/anie.200460936

Reference yield:

: 828915-86-2
Formic acid (5S,8R,9S,9aR)-8-(tert-butyl-dimethyl-silanyloxy)-9-[2-(dimethyl-phenyl-silanyl)-ethyl]-5-methyl-2-oxo-2,3,4,5,7,8,9,9a-octahydro-benzo[b]oxepin-6-ylmethyl ester

: 828915-89-5
(1R,5R,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[2-(dimethyl-phenyl-silanyl)-ethyl]-2-((S)-1-methyl-4-trityloxy-butyl)-3-trityloxymethyl-cyclohex-2-enol

Guidance literature:: Multi-step reaction with 2 steps

1.1: LiAlH₄ / diethyl ether / -10 - 0 °C

1.2: 91 percent / LiBH₄ / diethyl ether / 0 - 20 °C

2.1: 90 percent / DMAP; pyridine / CH₂Cl₂ / 40 h / 20 °C

With pyridine; dmap; lithium aluminium tetrahydride; In diethyl ether; dichloromethane;
DOI:10.1002/ejoc.200500739

Reference yield:

: (5S,8R,9S,9aR)-8-(tert-Butyl-dimethyl-silanyloxy)-9-[2-(dimethyl-phenyl-silanyl)-ethyl]-6-hydroxymethyl-5-methyl-2,3,4,5,7,8,9,9a-octahydro-benzo[b]oxepin-2-ol

: 828915-89-5
(1R,5R,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[2-(dimethyl-phenyl-silanyl)-ethyl]-2-((S)-1-methyl-4-trityloxy-butyl)-3-trityloxymethyl-cyclohex-2-enol

Guidance literature:: Multi-step reaction with 2 steps

1: LiBH₄ / diethyl ether / -10 °C

2: 91 percent / DMAP; pyridine / CH₂Cl₂ / 20 °C

With pyridine; dmap; lithium borohydride; In diethyl ether; dichloromethane;
DOI:10.1002/anie.200460936