Benzenepropanoic acid, b-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-b-(1-methylethenyl)-, ethyl ester

Base Information

Chemical Name:Benzenepropanoic acid, b-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-b-(1-methylethenyl)-, ethyl ester
CAS No.:828916-93-4
Molecular Formula:C21H34O3Si
Molecular Weight:362.57800
Hs Code.:

Synonyms:3-(tert-Butyl-dimethyl-silanyloxymethyl)-4-methyl-3-phenyl-pent-4-enoic acid ethyl ester;

Suppliers and Price of Benzenepropanoic acid, b-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-b-(1-methylethenyl)-, ethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzenepropanoic acid, b-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-b-(1-methylethenyl)-, ethyl ester

Chemical Property:

PSA：35.53000
LogP:5.47550

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Benzenepropanoic acid, b-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-b-(1-methylethenyl)-, ethyl ester

There total 2 articles about Benzenepropanoic acid, b-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-b-(1-methylethenyl)-, ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 78-39-7
Triethyl orthoacetate

: 828916-92-3
4-(t-butyldimethylsilyloxy)-3-phenyl-2-methyl-but-2-en-1-ol

: 828916-93-4
(+/-)-3-(t-butyldimethylsilyloxymethyl)-3-phenyl-4-methyl-pent-4-enoic acid ethyl ester

Guidance literature:: With propionic acid; at 135 - 140 ℃;
DOI:10.1002/ardp.200400875

Reference yield:

: 828916-91-2
4-(t-butyldimethylsilyloxy)-3-phenyl-2-methyl-but-2-enoic acid ethyl ester

: 828916-93-4
(+/-)-3-(t-butyldimethylsilyloxymethyl)-3-phenyl-4-methyl-pent-4-enoic acid ethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 91 percent / diisobutylaluminum hydride / CH₂Cl₂; hexane / 2 h / -50 °C

2: 78 percent / propionic acid / 140 °C

With diisobutylaluminium hydride; propionic acid; In hexane; dichloromethane;
DOI:10.1002/ardp.200400918