Silane, (1,1-dimethylethyl)dimethyl((2-(2-methyl-2-dodecen-5-ynyl)cyclohexyl)oxy)-, (1alpha,2beta(E))-

Base Information

Chemical Name:Silane, (1,1-dimethylethyl)dimethyl((2-(2-methyl-2-dodecen-5-ynyl)cyclohexyl)oxy)-, (1alpha,2beta(E))-
CAS No.:101859-08-9
Molecular Formula:C25H46 O Si
Molecular Weight:390.7176
Hs Code.:

Synonyms:101859-08-9;Silane, (1,1-dimethylethyl)dimethyl((2-(2-methyl-2-dodecen-5-ynyl)cyclohexyl)oxy)-, (1alpha,2beta(E))-

Suppliers and Price of Silane, (1,1-dimethylethyl)dimethyl((2-(2-methyl-2-dodecen-5-ynyl)cyclohexyl)oxy)-, (1alpha,2beta(E))-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Silane, (1,1-dimethylethyl)dimethyl((2-(2-methyl-2-dodecen-5-ynyl)cyclohexyl)oxy)-, (1alpha,2beta(E))-

Chemical Property:

Vapor Pressure:4.09E-07mmHg at 25°C
Boiling Point:427.4°Cat760mmHg
Flash Point:219.3°C
Density:0.88g/cm³
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:10
Exact Mass:390.331792621
Heavy Atom Count:27
Complexity:511

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCCCC#CCC=C(C)CC1CCCCC1O[Si](C)(C)C(C)(C)C
Isomeric SMILES:CCCCCCC#CC/C=C(\C)/C[C@H]1CCCC[C@@H]1O[Si](C)(C)C(C)(C)C

Technology Process of Silane, (1,1-dimethylethyl)dimethyl((2-(2-methyl-2-dodecen-5-ynyl)cyclohexyl)oxy)-, (1alpha,2beta(E))-

There total 6 articles about Silane, (1,1-dimethylethyl)dimethyl((2-(2-methyl-2-dodecen-5-ynyl)cyclohexyl)oxy)-, (1alpha,2beta(E))- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 629-05-0
n-octyne

: 101859-08-9
(1R*,2S*,(2E))-1-((tert-butyldimethylsilyl)oxy)-2-(2-methyldodec-1-en-5-ynyl)cyclohexane

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) n-BuLi / 1.) THF, HMPA, -78 deg C

2: 41 percent / Br₂ / CH₂Cl₂ / -78 °C

With n-butyllithium; bromine; In dichloromethane;
DOI:10.1021/jo00362a014

Reference yield:

: 74581-76-3
trimethyl(non-2-yn-1-yl)silane

: 101859-08-9
(1R*,2S*,(2E))-1-((tert-butyldimethylsilyl)oxy)-2-(2-methyldodec-1-en-5-ynyl)cyclohexane

Guidance literature:: Multi-step reaction with 2 steps

1: 41 percent / Br₂ / CH₂Cl₂ / -78 °C

With bromine; In dichloromethane;
DOI:10.1021/jo00362a014

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 101859-08-9
(1R*,2S*,(2E))-1-((tert-butyldimethylsilyl)oxy)-2-(2-methyldodec-1-en-5-ynyl)cyclohexane

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / TEA, DMAP / tetrahydrofuran; dimethylformamide / 24 h / Heating

2: 1.) Cp₂ZrCl₂, 2.) iodine / 1.) CH₂Cl₂, toluene, 21 deg C, 6 h, 2.) CH₂Cl₂, toluene, THF, 0 deg C, 20 min.

With dmap; zirconocene dichloride; TEA; iodine; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/jo00362a014