1-(4-Methanesulfonyl-phenyl)-2-nitro-ethanone oxime

Base Information

Chemical Name:1-(4-Methanesulfonyl-phenyl)-2-nitro-ethanone oxime
CAS No.:832717-24-5
Molecular Formula:C9H10N2O5S
Molecular Weight:258.255
Hs Code.:
DSSTox Substance ID:DTXSID60705524

Synonyms:1-(4-Methanesulfonyl-phenyl)-2-nitro-ethanone oxime;832717-24-5;SCHEMBL1245530;DTXSID60705524;MGCAXCXMIKIVHR-UHFFFAOYSA-N;N-{1-[4-(Methanesulfonyl)phenyl]-2-nitroethylidene}hydroxylamine

Suppliers and Price of 1-(4-Methanesulfonyl-phenyl)-2-nitro-ethanone oxime

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 1-(4-Methanesulfonyl-phenyl)-2-nitro-ethanone oxime

Chemical Property:

XLogP3:1.1
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:3
Exact Mass:258.03104260
Heavy Atom Count:17
Complexity:398

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CS(=O)(=O)C1=CC=C(C=C1)C(=NO)C[N+](=O)[O-]

Technology Process of 1-(4-Methanesulfonyl-phenyl)-2-nitro-ethanone oxime

There total 4 articles about 1-(4-Methanesulfonyl-phenyl)-2-nitro-ethanone oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.4%

: 832717-23-4
1-(4-methanesulfonyl-phenyl)-2-nitro-ethanone

: 832717-24-5
1-(4-methanesulfonyl-phenyl)-2-nitro-ethanone oxime

Guidance literature:: With hydroxylamine hydrochloride; In ethanol; acetic acid; at 20 ℃; for 3h; Heating / reflux;

Reference yield:

: 40913-92-6
4-methylsulfonylbenzoyl chloride

: 832717-24-5
1-(4-methanesulfonyl-phenyl)-2-nitro-ethanone oxime

Guidance literature:: Multi-step reaction with 3 steps

1: triethylamine / 0 - 20 °C

2: potassium tert-butylate / dimethyl sulfoxide / 0 - 20 °C

3: hydroxylamine hydrochloride; acetic acid / ethanol / Reflux

With hydroxylamine hydrochloride; potassium tert-butylate; acetic acid; triethylamine; In ethanol; dimethyl sulfoxide;
DOI:10.1016/j.bmcl.2011.03.007

Reference yield:

: 4052-30-6
4-methylsulfonylbenzoic acid

: 832717-24-5
1-(4-methanesulfonyl-phenyl)-2-nitro-ethanone oxime

Guidance literature:: Multi-step reaction with 4 steps

1: phosgene / dichloromethane; N,N-dimethyl-formamide / 0 - 20 °C

2: triethylamine / 0 - 20 °C

3: potassium tert-butylate / dimethyl sulfoxide / 0 - 20 °C

4: hydroxylamine hydrochloride; acetic acid / ethanol / Reflux

With phosgene; hydroxylamine hydrochloride; potassium tert-butylate; acetic acid; triethylamine; In ethanol; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide;
DOI:10.1016/j.bmcl.2011.03.007