7-Bromobicyclo[2.2.1]hept-2-yl acetate

Base Information

Chemical Name:7-Bromobicyclo[2.2.1]hept-2-yl acetate
CAS No.:10389-63-6
Molecular Formula:C₉H₁₃BrO₂
Molecular Weight:233.105
Hs Code.:
NSC Number:110579
DSSTox Substance ID:DTXSID80296626
Mol file:10389-63-6.mol

Synonyms:10389-63-6;NSC 110579;7-bromobicyclo[2.2.1]hept-2-yl acetate;NSC110579;DTXSID80296626;NSC-110579

Suppliers and Price of 7-Bromobicyclo[2.2.1]hept-2-yl acetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of 7-Bromobicyclo[2.2.1]hept-2-yl acetate

Chemical Property:

Vapor Pressure:0.0146mmHg at 25°C
Boiling Point:257.3°C at 760 mmHg
Flash Point:109.4°C
Density:1.46g/cm³
XLogP3:2.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:232.00989
Heavy Atom Count:12
Complexity:205

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)OC1CC2CCC1C2Br

Technology Process of 7-Bromobicyclo[2.2.1]hept-2-yl acetate

There total 12 articles about 7-Bromobicyclo[2.2.1]hept-2-yl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2-exo-Acetoxy-8,9,10-trinorbornan-7-anti-carbonsaeure

: 10389-63-6,90674-89-8
anti-7-bromo-exo-2-norbornyl acetate

Guidance literature:: With bromine; mercury(II) oxide; In dichloromethane; at 80 ℃; for 3h;
DOI:10.1002/hlca.19830660711

Reference yield:

: 2-exo-Brom-5-endo-hydroxy-8,9,6-trinorbornan-7-anti-carbonsaeure

: 10389-63-6,90674-89-8
anti-7-bromo-exo-2-norbornyl acetate

Guidance literature:: Multi-step reaction with 7 steps

1: 73 percent / H₂ / Pd/C / aq. NaOH

2: 98 percent / diethyl ether / 0.25 h

3: 89 percent / pyridine / 48 h / 22 °C

4: formic acid / 15 h / 70 °C

5: 54 percent / NaOH / methanol; H₂O / 1 h / Heating

6: 86 percent / pyridine / 12 h / Ambient temperature

7: HgO, Br₂ / CH₂Cl₂; various solvent(s) / 3 h / 80 °C

With pyridine; sodium hydroxide; hydrogen; bromine; mercury(II) oxide; palladium on activated charcoal; In methanol; sodium hydroxide; formic acid; diethyl ether; dichloromethane; water;
DOI:10.1002/hlca.19830660711

Reference yield:

: 2-exo-Brom-5-oxonorbornan-7-syn-carbonsaeure

: 10389-63-6,90674-89-8
anti-7-bromo-exo-2-norbornyl acetate

Guidance literature:: Multi-step reaction with 8 steps

1: 71 percent / NaBH₄ / propan-2-ol; H₂O / 3 h / Ambient temperature

2: 73 percent / H₂ / Pd/C / aq. NaOH

3: 98 percent / diethyl ether / 0.25 h

4: 89 percent / pyridine / 48 h / 22 °C

5: formic acid / 15 h / 70 °C

6: 54 percent / NaOH / methanol; H₂O / 1 h / Heating

7: 86 percent / pyridine / 12 h / Ambient temperature

8: HgO, Br₂ / CH₂Cl₂; various solvent(s) / 3 h / 80 °C

With pyridine; sodium hydroxide; sodium tetrahydroborate; hydrogen; bromine; mercury(II) oxide; palladium on activated charcoal; In methanol; sodium hydroxide; formic acid; diethyl ether; dichloromethane; water; isopropyl alcohol;
DOI:10.1002/hlca.19830660711