Technology Process of Benzene, (6-methyl-3,5-heptadienyl)-, (Z)-
There total 5 articles about Benzene, (6-methyl-3,5-heptadienyl)-, (Z)- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
2,4-dinitrobenzenesulfenyl chloride; triethylamine;
In
dichloromethane;
at 25 ℃;
for 16h;
Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1021/ja00389a028
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 1.) LDA / 1.) THF, 0 deg C, 30 min, 2.) 75 min
2: 30percent H2O2, pyridine / CH2Cl2; H2O / 0.17 h
3: Et3N, 2,4-dinitrobenzenesulfenyl chloride / CH2Cl2 / 16 h / 25 °C
With
pyridine; dihydrogen peroxide; 2,4-dinitrobenzenesulfenyl chloride; triethylamine; lithium diisopropyl amide;
In
dichloromethane; water;
DOI:10.1021/ja00389a028
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 1.) LDA / 1.) THF, 0 deg C, 30 min, 2.) 75 min
2: 30percent H2O2, pyridine / CH2Cl2; H2O / 0.17 h
3: Et3N, 2,4-dinitrobenzenesulfenyl chloride / CH2Cl2 / 16 h / 25 °C
With
pyridine; dihydrogen peroxide; 2,4-dinitrobenzenesulfenyl chloride; triethylamine; lithium diisopropyl amide;
In
dichloromethane; water;
DOI:10.1021/ja00389a028