68099-28-5Relevant academic research and scientific papers
Stereoselective Suzuki-Miyaura cross-coupling reactions of potassium alkenyltrifluoroborates with alkenyl bromides
Molander, Gary A.,Felix, Luciana A.
, p. 3950 - 3956 (2007/10/03)
The stereoselective synthesis of conjugated dienes using air-stable potassium alkenyltrifluoroborates as coupling partners is described. The palladium-catalyzed cross-coupling reaction of potassium (E)- and (Z)-alkenyltrifluoroborates with either (E)- or
Use of Samarium Diiodide as an Alternative to Sodium/Mercury Amalgam in the Julia-Lythgoe Olefination
Keck, Gary E.,Savin, Kenneth A.,Weglarz, Michael A.
, p. 3194 - 3204 (2007/10/02)
Studies into the use of samarium diiodide (SmI2) in the reductive elimination of 1,2-acetoxy sulfones and the reductive cleavage of vinyl sulfones are reported.Parallel investigations with sodium/mercury amalgam (Na/Hg) revealed over-reduction in several
