2,8-Decadienedioic acid, 4-[2-(trimethylsilyl)ethoxy]-, 1-[(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl] 10-(phenylmethyl) ester, (2E,4R,8E)-

Base Information

Chemical Name:2,8-Decadienedioic acid, 4-[2-(trimethylsilyl)ethoxy]-, 1-[(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl] 10-(phenylmethyl) ester, (2E,4R,8E)-
CAS No.:837428-24-7
Molecular Formula:C38H54O5Si
Molecular Weight:618.929
Hs Code.:

2,8-Decadienedioic acid, 4-[2-(trimethylsilyl)ethoxy]-,
1-[(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl]
10-(phenylmethyl) ester, (2E,4R,8E)-

Synonyms:

Suppliers and Price of 2,8-Decadienedioic acid, 4-[2-(trimethylsilyl)ethoxy]-, 1-[(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl] 10-(phenylmethyl) ester, (2E,4R,8E)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,8-Decadienedioic acid, 4-[2-(trimethylsilyl)ethoxy]-, 1-[(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl] 10-(phenylmethyl) ester, (2E,4R,8E)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2,8-Decadienedioic acid, 4-[2-(trimethylsilyl)ethoxy]-, 1-[(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl] 10-(phenylmethyl) ester, (2E,4R,8E)-

There total 15 articles about 2,8-Decadienedioic acid, 4-[2-(trimethylsilyl)ethoxy]-, 1-[(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl] 10-(phenylmethyl) ester, (2E,4R,8E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2916-68-9
2-(Trimethylsilyl)ethanol

: 837428-39-4
10-benzyl 1-[(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl] (2E,4R,8E)-4-[(diphenylphosphoryl)oxy]deca-2,8-dienedioate

: 10-benzyl 1-[(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl] (2E,4S,8E)-4-[2-(trimethylsilyl)ethoxy]deca-2,8-dienedioate

: 837428-24-7
10-benzyl 1-[(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl] (2E,4R,8E)-4-[2-(trimethylsilyl)ethoxy]deca-2,8-dienedioate

Guidance literature:: With 2.9-dimethyl-1,10-phenanthroline; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In dichloromethane; at 20 ℃; for 3h;
DOI:10.1021/ol0479242

Reference yield:

: 2916-68-9
2-(Trimethylsilyl)ethanol

: 881663-83-8
10-benzyl 1-[(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl] (2Z,4S,8E)-4-[(diphenylphosphoryl)oxy]deca-2,8-dienedioate

: 10-benzyl 1-[(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl] (2E,4S,8E)-4-[2-(trimethylsilyl)ethoxy]deca-2,8-dienedioate

: 837428-24-7
10-benzyl 1-[(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl] (2E,4R,8E)-4-[2-(trimethylsilyl)ethoxy]deca-2,8-dienedioate

Guidance literature:: With 2.9-dimethyl-1,10-phenanthroline; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In dichloromethane; at 20 ℃; for 3h;
DOI:10.1021/ol0479242

Reference yield:

: 100-73-2
acrolein dimer

: 837428-24-7
10-benzyl 1-[(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl] (2E,4R,8E)-4-[2-(trimethylsilyl)ethoxy]deca-2,8-dienedioate

Guidance literature:: Multi-step reaction with 5 steps

1: KHMDS; 18-crown-6 / tetrahydrofuran; toluene / 7 h / -78 °C

2: 81 percent / p-toluenesulfonic acid monohydrate; water / tetrahydrofuran / 20 h / 32 °C

3: LiHMDS / toluene; tetrahydrofuran / 14 h / 0 °C

4: 91 percent / imidazole; DMAP / 1,2-dichloro-ethane; tetrahydrofuran / 16 h / 60 °C

5: neocuproine / Pd₂(dba)3 / CH₂Cl₂ / 3 h / 20 °C

With 1H-imidazole; dmap; 2.9-dimethyl-1,10-phenanthroline; 18-crown-6 ether; water; potassium hexamethylsilazane; toluene-4-sulfonic acid; lithium hexamethyldisilazane; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In tetrahydrofuran; dichloromethane; 1,2-dichloro-ethane; toluene; 3: Horner-Wadsworth-Emmons reaction;
DOI:10.1021/ol0479242