1,1,6,6,11,11,16,16-Octaphenyl-1,6,11,16-tetrastannacycloicosane

Base Information

Chemical Name:1,1,6,6,11,11,16,16-Octaphenyl-1,6,11,16-tetrastannacycloicosane
CAS No.:83802-01-1
Molecular Formula:C₆₄H₇₂Sn₄
Molecular Weight:1316.12
Hs Code.:
DSSTox Substance ID:DTXSID50517395
Wikidata:Q82379373

Synonyms:83802-01-1;DTXSID50517395;1,1,6,6,11,11,16,16-Octaphenyl-1,6,11,16-tetrastannacycloicosane

Suppliers and Price of 1,1,6,6,11,11,16,16-Octaphenyl-1,6,11,16-tetrastannacycloicosane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,1,6,6,11,11,16,16-Octaphenyl-1,6,11,16-tetrastannacycloicosane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:8
Exact Mass:1314.17116
Heavy Atom Count:68
Complexity:1050

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1CC[Sn](CCCC[Sn](CCCC[Sn](CCCC[Sn](C1)(C2=CC=CC=C2)C3=CC=CC=C3)(C4=CC=CC=C4)C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7)(C8=CC=CC=C8)C9=CC=CC=C9

Technology Process of 1,1,6,6,11,11,16,16-Octaphenyl-1,6,11,16-tetrastannacycloicosane

There total 5 articles about 1,1,6,6,11,11,16,16-Octaphenyl-1,6,11,16-tetrastannacycloicosane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 110-52-1
1,4-dibromo-butane

: 83802-02-2
(C₆H₅)2Sn(Li)(CH₂)4Sn(Li)(C₆H₅)2

: 68970-21-8
1,1,6,6-tetraphenyl-1,6-distannacyclodecane

: 83802-01-1
1,1,6,6,11,11,16,16-octaphenyl-1,6,11,16-tetrastannaeicosane

Guidance literature:: In tetrahydrofuran; (N2); soln. of dilithium compd. added over 1 h to dibromo-compd. soln. at 0°C, allowed to warm to room temp., stirred for 14 h; satd. aq. NH4Cl added at 0°C, aq. layer extd. (ether), combined ethereal solns. washed (satd. aq. NaCl), dried (MgSO4), filtered, concd., chromd., recrystd. (hexane); elem. anal.;
DOI:10.1021/om00079a003

Reference yield: 43.0%

: 83815-91-2
1,4-bis(bromodiphenylstannyl)butane

: 83815-92-3
1,14-dichloro-5,5,10,10-tetraphenyl-5,10-distannatetradecane

: 83802-01-1
1,1,6,6,11,11,16,16-octaphenyl-1,6,11,16-tetrastannaeicosane

Guidance literature:: With lithium; In tetrahydrofuran; (Ar or N2); ((C6H5)2Sn(Br)C2H4)2 added to excess Li in THF, dild. with THF, added for 2 h to THF soln. of (Cl(CH2)4Sn(C6H5)2C2H4)2 (1 molar equiv) at 0°C, warmed to room temp. for 12 h; treated with satd. aq. NH4Cl, aq. phase extd. (ether), combined org. phases washed with satd. aq. NaCl, dried (MgSO4), evapd. (vac.), purified by reverse-phase chromy. (THF/MeCN);
DOI:10.1021/om00073a039

Reference yield: 43.0%

: 83802-02-2
(C₆H₅)2Sn(Li)(CH₂)4Sn(Li)(C₆H₅)2

: 83815-92-3
1,14-dichloro-5,5,10,10-tetraphenyl-5,10-distannatetradecane

: 83802-01-1
1,1,6,6,11,11,16,16-octaphenyl-1,6,11,16-tetrastannaeicosane

Guidance literature:: In tetrahydrofuran; (N2); soln. of dilithium compd. added over 2 h to soln. of dichloro-compd. at 0°C, allowed to warm to room temp., stirred for 18 h; satd. aq. NH4Cl added at 0°C, aq. layer extd. (ether), combined ethereal solns. washed (satd. aq. NaCl), dried (MgSO4), filtered, concd., chromd., recrystd. (hexane/ether); elem. anal.;
DOI:10.1021/om00079a003